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1、氯化橡胶涂料氯化橡胶涂料在集装箱行业的应用在集装箱行业的应用中远关西涂料中远关西涂料中远关西涂料中远关西涂料 刘会成刘会成刘会成刘会成 集装箱涂料相关标准集装箱涂料相关标准3 集装箱行业介绍集装箱行业介绍1氯化橡胶类涂料的缺陷及改进要求氯化橡胶类涂料的缺陷及改进要求4 集装箱涂装配套集装箱涂装配套2Content集装箱的诞生雏形雏形创立创立成长成长 成熟成熟1801 Dr. James AndersonWord War IIWeapons Transportation19561966Aril 26th,1956“Macedonia”(Pan-Atlantic Steamship Co.)Oct
2、. 1957“Gateway City”19661980sConstruction of Container Terminal“Door to Door”InternationalSystematic1980sContainerization,more than 80%Joint Venture Global Alliance集装箱制造业转移1970s Starting in USA, and soon transferred to Europe中国韩国/台湾日本日本欧美欧美1970s1980s, Japan took over the baton1980s1990s, Korea was t
3、he main force in the container manufacturing1990s, More than 95% of container were producted in China集装箱在中国April, 1955 Short-term trial operation1973 Maritime container trasportSept. 1973 1st international container1970s起步起步1980s成长成长1990s发展发展世界世界集装箱集装箱运输和运输和制造业制造业焦点焦点2011年全世界年全世界10个最大的集装箱港口中，有个最大的集装
4、箱港口中，有6个在中国个在中国上海上海(1), 香港香港(3),深圳深圳(4),宁波宁波(6),青岛青岛(7),广州广州(8)中远中远COSCO, 中海中海China Shipping, 东方海外东方海外OOCL(Hong Kong), 长荣长荣Evergreen(Taiwan)a，万海，万海Wan Hai(Taiwan) 等公司位居世界航运公司前等公司位居世界航运公司前20强。强。集装箱制造业近年来集装箱产量在目前的管理水平下，每TEU集装箱约使用油漆65Kg。集装箱涂料现状集装箱涂料市场份额集装箱涂料现状集装箱结构集装箱生产工艺集装箱生产工艺集装箱涂料现状集装箱涂料配套 涂料品种涂料品种干
5、膜厚度（干膜厚度（m）内表面内表面外表面外表面1环氧富氧富锌车间底漆底漆10102环氧富氧富锌底漆底漆20203环氧内面漆环氧内面漆454环氧中间漆环氧中间漆405丙丙烯酸面漆（酸面漆（氯化橡胶面漆）化橡胶面漆）40合合计75110集装箱涂料的沿革涂料 1960 1980 1990 2004面漆醇酸氯化橡胶化橡胶 丙烯酸中间漆环氧底漆醇酸等氯化橡胶化橡胶环氧环氧富锌With the improvment of container owners requirment, the coating system tend to a uniform, which is “epoxy zinc rich
6、primer+epoxy mid-coat+acrylic top-coat”.氯化橡胶和丙烯酸面漆对比氯化橡胶和丙烯酸面漆对比品种氯化橡胶丙烯酸防腐性好稍差施工性差好柔韧性好差成本稍高较低丙烯酸面漆的缺陷丙烯酸面漆的缺陷l柔韧性差丙烯酸面漆的缺陷丙烯酸面漆的缺陷l 防腐性略差盐雾600hr 氯化橡胶面漆 丙烯酸面漆氯化橡胶面漆的缺陷氯化橡胶面漆的缺陷环保问题柔韧性-增韧剂的选择施工性能遇水泛白施工性能修补时的色差氯化橡胶面漆的缺陷氯化橡胶面漆的缺陷施工性能修补时的色差 光泽差异造成造成视觉色差咬底 当用醇酸树脂作为增塑剂时，堆场修补（下线8小时至24小时）会出现咬底，影响施工进度。氯化橡胶面
7、漆的缺陷氯化橡胶面漆的缺陷施工性能遇水泛白氯化橡胶面漆的改进方向氯化橡胶面漆的改进方向采用环保的方法生产氯化橡胶树脂降低成本选用合适的增塑剂集装箱涂料标准-Konstandt LabKonstandt LabTestTest methodEvolution & RequirementResultScoreAbrasion resistanceASTM D 10441000cycles, 250g, CS 10 wheel0-1011-25251086Corrosion resistanceRust from scribe markASTM B117ASTM 165401.0mm2.0mm3.0
8、mm4.0mm5.0mm6.0mm10876544BlisterASTM B117ASTM 1654None1-23-78-1011-2526-401077643TestTest methodEvolution & RequirementResultScoreAccelerated weatheringColor changeASTM E 42(600hr)ASTM D 2244E2E3106Loss in glossASTM E 42(600hr)ASTM D 5230-10%11-24%25%1086FlexibilityASTM D 1713180 deg. 12.5mmOriginal
9、No crackingSlight crackingCracking1051After accelerated weathering(600hr)No crackingSlight crackingCracking1051集装箱涂料标准-Konstandt LabKonstandt LabTestTest methodEvolution & RequirementResultScoreAdhesionDIN 53151划格附着力OriginalNo removal5% removal15% removal35% removal50% removal108642After accelerated
10、 weathering(600hr)No removal5% removal15% removal35% removal50% removal108642Salt water resistance5%NaCl,168hr,25No effectSlight dullingBlistering and/or other defects1062集装箱涂料标准-Konstandt LabKonstandt LabTestTest methodEvolution & RequirementResultScoreImpact resistanceASTM 2794Cm-Kg at FailureOrig
11、inal7563-7450-625010864After accelerated weathering(600hr)7563-7450-625010864HardnessASTM D 3363(Pencil scratch)Oxidized and catalyzed coatings6H5H4H3H10642Evaporation coatings4H3H2HH10864集装箱涂料标准-Konstandt LabKonstandt LabIICLIICL：INSTITUTE OF INTERNATIONAL CONTAINER LESSORSINSTITUTE OF INTERNATIONA
12、L CONTAINER LESSORS 集装箱涂料标准-IICLIICLIICL全称为国际集装箱出租商协会全称为国际集装箱出租商协会 成立于1971年，本部设立于华盛顿，随着第一代集装箱和集装箱船的快速发展，集装箱的安全和质量成为集装箱货运体系中至关重要的一个环节。在美国，IICL同美国国务院和海岸巡逻队一同制定国际集装箱安全公约（CSC）的各项条款和美国集装箱安全法案 Panel SpecimenPanel SpecimenSize:76*152*1.6mmSize:76*152*1.6mmSbustrate:G3101(SS41)Sbustrate:G3101(SS41)Blasted:S
13、a2 Blasted:Sa2 RoughRough：25-40 Rmax 8025-40 Rmax 80集装箱涂料标准-IICLIICLExterior MethodExterior Method8h UV at 60 （UVA340） 4h condensation at 50 Repeat sub cycle for 72hrs4h wet at 302h dry at 40 Repeat sub cycle for 96hrs8 Times56days集装箱涂料标准-IICLIICL4h wet at 302h dry at 40 Repeat sub cycle for 96hrs8
14、Times56daysInterior MethodInterior Method8h dry/dark at 60 4h condensation (100%RH)at 60 Repeat sub cycle for 72hrs集装箱涂料标准-IICLIICLBlister Test (ASTM D714)Blister Test (ASTM D714)No.10No.8No.6No.4No.2None20Few151050Medium1050Medium Dense50Dense0集装箱涂料标准-IICLIICLRust Test (ASTM D610)Rust Test (ASTM D6
15、10)Rust GradeUnit ValueGrade 1010Grade 99Grade 86Grade 73Grade 60集装箱涂料标准-IICLIICLUndercutting Test (ASTM D1654)Undercutting Test (ASTM D1654)Average Scribe CreepUnit Value0-1mm102-3mm94-6mm77-9mm510-11mm311mm0集装箱涂料标准-IICLIICLAdhesion Test Adhesion Test （ASTM D3359ASTM D3359）ASTM ClassificationUnit V
16、alue5B154B123B72B31B or 0B2集装箱涂料标准-IICLIICLImpact Resistance TestImpact Resistance Test(ASTM D 2794) (ASTM D 2794) Exterior/Interior Reverse ImpactExterior/Interior Reverse ImpactKg M at FailureUnit Value0.23100.17-0.2280.12-0.1660.06-0.1140.03-0.0520. 02 or Less0集装箱涂料标准-IICLIICLImpact Resistance Te
17、stImpact Resistance Test(ASTM D 2794) (ASTM D 2794) Interior Forward ImpactInterior Forward ImpactKg M at FailureUnit Value0.58100.52-0.5790.46-0.5180.40-0.4570.35-0.3960.29-0.3450.28 or Less0集装箱涂料标准-IICLIICLAbrasion Test (ASTM D4060)Abrasion Test (ASTM D4060)Weight LossUnit Value0-100mg15101-150mg1
18、2151-200mg9200mg0集装箱涂料标准-IICLIICLColor Test Color Test （ASTM D2244ASTM D2244）Color Change（E）Unit Value33425150集装箱涂料标准-IICLIICLGloss Test (ASTM D523)Gloss Test (ASTM D523)涂膜涂膜涂膜涂膜oGloss ChangeUnit Value0-20%221-30%130%0集装箱涂料标准-IICLIICLTesting Scoring Table Testing Scoring Table Exterior Paint SystemE
19、xterior Paint SystemGroupScribed or notMaxMinTest WeightScore FactorCorrosive Group7555Blister TestUnscribed15%0.75Rusting Test25%2.50Undercutting TestScribe30%3.00Mechanical Group2515Adhesion TestUnscribed15%1.00Impact Test10%1.00Cosmetic Group5NoneColor TestUnscribed3%1.00Gloss Test2%1.00Total For
20、 All Test10070100%集装箱涂料标准-IICLIICLTesting Scoring Table Testing Scoring Table Interior Paint SystemInterior Paint SystemGroupScribed or notMaxMinTest WeightScore FactorCorrosive Group5540Blister TestUnscribed20%1.00Rusting Test15%1.50Undercutting TestScribe20%2.00Mechanical Group4530Adhesion TestUnscribed15%1.00Impact 15%1.50Abrasion Test15%1.00Total For All Test10070100%集装箱涂料标准-IICLIICL集装箱涂料标准-JH/T E01-2008JH/T E01-2008集装箱涂料技术指标涂层技术要求集装箱涂料标准-JH/T E01-2008JH/T E01-2008
