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1、MATERIAL SAFETY DATA SHEET Date Printed: 04/05/2007 Date Updated: 02/02/2006 Version 1.4 Section 1 - Product and Company Information Product Name ETHYLENE CARBONATE, 98% Product Number E26258 Brand ALDRICH Company Sigma-Aldrich Address 3050 Spruce Street SAINT LOUIS MO 63103 US Technical Phone: 800-
2、325-5832 Fax: 800-325-5052 Emergency Phone: 314-776-6555 Section 2 - Composition/Information on Ingredient Substance Name CAS # SARA 313 ETHYLENE CARBONATE 96-49-1 No Formula C3H4O3 Synonyms Cyclic ethylene carbonate * 1,3-Dioxolan-2-one *Dioxolone-2 * Ethylene carbonate * Ethylene carbonic acid * E
3、thylene glycol carbonate * Ethylene glycol, cyclic carbonate * Ethylenester kyseliny uhlicite (Czech) * Glycol carbonate RTECS Number: FF9550000 Section 3 - Hazards Identification EMERGENCY OVERVIEW Irritant. Irritating to eyes. HMIS RATING HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 NFPA RATING HEALTH:
4、 1 FLAMMABILITY: 0 REACTIVITY: 0 For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breath
5、ing give artificial respiration. If breathing is difficult, give oxygen. DERMAL EXPOSURE In case of contact, immediately wash skin with soap and copious amounts of water. EYE EXPOSURE In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. Section 5 - Fire F
6、ighting Measures FLASH POINT 289.4 F 143 C Method: closed cup AUTOIGNITION TEMP N/A FLAMMABILITY N/A EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing
7、 to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. Section 9 - Physical/Chemical Properties Appearance Color: Colorless Form: Crystals Property Value At Temperature or Pressure Molecular Weight 88.06 AMU pH 5.5 - 7.0 BP/BP Range 243.0 - 244.0 C 740 m
8、mHg MP/MP Range 35 C Freezing Point N/A Section 6 - Accidental Release Measures PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear respirator, chemical safety goggles, rubber gloves. METHODS FOR CLEANING UP Sweep up, place in a bag and hold for dust. Ventilate area and wash spill complete. rubber boots, an
9、d heavy waste site disposal. Avoid raising after material pickup is Section 7 - Handling and Storage HANDLING User Exposure: Do not breathe dust. and clothing. Avoid prolonged or repeated exposure. STORAGE Suitable: Keep tightly closed. Avoid contact with eyes, skin, Section 8 - Exposure Controls /
10、PPE ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators
11、 are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Hand: Compatible chemical-resistant gloves. Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Vapor Pressure N/A Vapor Density 3.04 g/l Saturated Vapor Conc. N/A SG/Density 1.321 g/cm3
12、 Bulk Density N/A Odor Threshold N/A Volatile% N/A VOC Content N/A Water Content N/A Solvent Content N/A Evaporation Rate N/A Viscosity N/A Surface Tension N/A Partition Coefficient N/A Decomposition Temp. N/A Flash Point 289.4 F 143 C Method: closed cup Explosion Limits N/A Flammability N/A Autoign
13、ition Temp N/A Refractive Index N/A Optical Rotation N/A Miscellaneous Data N/A Solubility Solubility in Water:1 M in H2O, 20 C clear, colorless N/A = not available Section 10 - Stability and Reactivity STABILITY Materials to Avoid: Strong oxidizing agents, Acids, Bases, Reducing agents. HAZARDOUS D
14、ECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur Section 11 - Toxicological Information ROUTE OF EXPOSURE Skin Contact: May cause skin irritation. Skin Absorption: May be harmful if absorbed through the
15、skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. TOXICITY DATA Oral Rat 100
16、00 mg/kg LD50 dioxide. Skin Rabbit 3000 mg/kg LD50 IRRITATION DATA Skin Rabbit 660 mg Remarks: Open irritation test Section 12 - Ecological Information No data available. Section 13 - Disposal Considerations APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Contact a licensed professional w
17、aste disposal of this material. Dissolve or mix the material solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. Section 14 - Transport Information DOT Proper Shipping Name: None Non-Hazardous for Tran
18、sport: This substance is considered to be non-hazardous for transport. IATA Non-Hazardous for Air Transport: Non-hazardous Section 15 - Regulatory Information EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respirator
19、y system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US CLASSIFICATION AND LABEL TEXT Indication of Danger: Irritant. Risk Statements: Irritating to eyes. Safety Statements: In
20、case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. UNITED STATES REGULATORY INFORMATION SARA LISTED: No TSCA INVENTORY ITEM: Yes CANADA REGULATORY INFORMATION WHMIS Classification: This product has been classified in accordan
21、ce with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. DSL: Yes NDSL: No Section 16 - Other Information service to dispose with a combustible for air transport. DISCLAIMER For R&D use only. Not for drug, household or other uses. WARRANTY The above info
22、rmation is believed to be correct but does not purport to be all inclusive and shall be used only information in this document is based on the present knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of th
23、e product. Sigma-Aldrich Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse or packing slip for additional terms and conditions of sale. Copyright 2007 Sigma-Aldrich Co. License granted to paper copies for internal use only. as a guide. The state of our side of invoice make unlimited
