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1、Item Number: 152 Page06/10/2008 of 51Material Safety Data SheetSection 1: PRODUCT AND COMPANY IDENTIFICATIONVi-Jon IncorporatedPhone: 314-427-10008515 Page AvenueIn Case of Spill Emergency Contact:Saint Louis, MO 63114Chemtrec:1-800-424-9300Product Name: Germ-X Hand Sanitizer IPA FreeProduct Code:15
2、2Product Use: Hand SanitizerIssue Date: 06/10/2008Supersedes Date:December 6, 2006Section 2: HAZARDS IDENTIFICATIONEMERGENCY OVERVIEW: Keep out of reach of children.Appearance/Odor: Clear thick colorless gel with floral scentWARNING:Flammable (ethyl alcohol)Target (ethyl alcohol) respiratory system,
3、 skin, eyes, CNS, liver, blood and reproductive system.Potential Health Effects: See Section 11 for more information.Symptoms of Exposure:Inhalation:May cause irritation of the respiratory tract.Ingestion:May cause nausea, vomiting and diarrhea.Eyes:May cause irritation to the eyes.Skin:None expecte
4、d.This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARCor NTP.This material contains a component that is considered hazardous by the OSHA HazardCommunication Standard (29 CFR 1910.1200).Potential Environmental Effects: See Section 12 for more information.Sect
5、ion 3: COMPOSITION/INFORMATION ON INGREDIENTSComponent CAS# % by Wt.Ethyl Alcohol64-17-5 59%Item Number: 152 Page06/10/2008 of 52Section 4: FIRST AID MEASURESEmergency first aid procedures by route of exposure:Inhalation:If symptoms are experience, remove source of contamination or move victim tofre
6、sh air. If affected person is not breathing, apply artificial respiration. Ifbreathing is difficult, give oxygen. Get medical attention.Ingestion:Do not induce vomiting. If the material is swallowed, get medical attention oradvice.Skin:If irritation is experienced, flush with water. If irritation pe
7、rsists, get medicalattention.Eyes:Immediately flush eyes with water for at least 15 minutes while holding eyelidsopen. If symptoms persist, get medical attention.Section 5: FIRE FIGHTING MEASURESFlash Point: 71 F (21.6 C)Method Used: ASTM D 93Lower Flammable Limit: 3.3 (Volume % in air)Upper Flammab
8、le Limit: 19.0 (Volume % in air)Auto Ignition: (Ethyl Alcohol) 363 CFlammability Classification: Flammable Liquid BExtinguishing Media: Use methods appropriate for the surrounding fire. Consider water sprayor fog, carbon dioxide, dry chemical powder, or alcohol resistant foam.Products of Combustion:
9、 Upon decomposition this product may emit carbon dioxide, carbonmonoxide and/or low molecular weight hydrocarbons.Fire Fighting Equipment/Instructions: Wear protective clothing and equipment suitable for thesurrounding fire, including helmet, facemask, and self contained breathing apparatus.NFPA Rat
10、ing: Health:2 Fire: 3 Reactivity:0Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = SevereSection 6: ACCIDENTAL RELEASE MEASURESPersonal Precautions: For large spills wear gloves, safety glasses and when levels exceedOSHA PEL use appropriate NIOSH approved respiratory protection. Kee
11、p unnecessarypersonnel away. Eliminate all sources of ignition or flammables that may come into contact witha spill of this material.Environmental Precautions: Prevent discharge to open waters.Method for Containment: Absorb spilled liquid in suitable non-flammable inert material such asclay, vermicu
12、lite or diatomaceous earth.Methods for Clean-Up: Ventilate area of leak or spill. Use spark-proof tools to sweep or scrapeup and containerize in approved chemical waste container. Wash spill area with water.Section 7: HANDLING AND STORAGEHandling: Keep away from heat, sparks and flame. Prevent conta
13、ct with eyes. Avoidinhalation.Storage: Keep the container tightly closed and in a cool, well ventilated place.Item Number: 152 Page06/10/2008 of 53Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONExposure GuidelinesEthyl Alcohol (64-17-5)ACGIH:1,000 ppm TWAOSHA:1,000 ppm TWA; 1,900 mg/m3 TWAEngineeri
14、ng Controls: Normal room ventilation is usually adequate under normal use.Personal Protective Equipment (PPE)Eye/Face Protection: None needed under normal use.Skin Protection: None needed under normal use.Respiratory Protection: None needed under normal use.General Hygiene Considerations: None neede
15、d under normal use.Section 9: PHYSICAL AND CHEMICAL PROPERTIESAppearance/Color: Clear Translucent Clear thick colorless gelOdor : floralPhysical State:GelpH : Not Available.Vapor Density: (Ethyl Alcohol) 1.6Boiling Point: (Ethyl Alcohol) 78.5 CVapor Pressure: (Ethyl Alcohol) 57.3 hPa at 20 CMelting
16、Point: (Ethyl Alcohol) -114.1 CFreezing Point: Not AvailableFlash Point (see section 5)Flammability Properties (see section 5)Solubility (in water): SolubleSpecific Gravity 25 C: 0.880-0.920Evaporation Rate: Not AvailableOctanol/Water partition coefficient (Kow): (Ethyl Alcohol): - 0.32Auto-ignition
17、 temperature: (Ethyl Alcohol) 363 CDecomposition temperature: Not AvailableSection 10: STABILITY AND REACTIVITYStability: Stable under normal ambient temperatures 70 C (21 C)Condition to Avoid: Avoid excessive heat or sources of ignition.Incompatible Materials: This product reacts with strong acid,
18、strong bases, and oxidizingagents.Hazardous Decomposition: upon decomposition, this product evolves carbon monoxide, carbondioxide, and/or low weight hydrocarbons.Hazardous Reactions: Hazardous polymerization will not occur.Item Number: 152 Page06/10/2008 of 54Section 11: TOXICOLOGY INFORMATIONACUTE
19、 EFFECTS:A: General Product informationProduct contains ethyl alcohol.B: Component Analysis LD50Ethyl Alcohol (64-17-5)Oral LD50 Rat: 7060 mg/kgCHRONIC EFFECTS:ComponentEthyl Alcohol (64-17-5)Carcinogenicity: ACGIH A4 Not Classifiable as a Human CarcinogenNeurotoxicity: This product contains ethyl a
20、lcohol, a central nervous system target.Mutagenicity: No information available for product.Reproductive: No information available for product.Developmental: Ethyl alcohol is a developmental toxin when consumed duringpregnancy.Target Organs: When consumed, ethyl alcohol can target therespiratory syst
21、em, skin, eyes, CNS, liver, blood and reproductive system.Section 12: ECOLOGICAL INFORMATIONEcotoxicity: Ethyl Alcohol (64-17-5)96 hour LC50 Oncorhynchus mykiss: 12,900 mg/L (flow-through) (30days old)96 hour LC50 Pimephales promelas 14.2 mg/L5 min EC50 Photobacterium phosphoreum: 35,470 mg/L30 min
22、EC50 Photobacterium phosphoreum: 34,634 mg/L48 hour EC50 Daphnia magna: 9,268 mg/L24 hour EC50 Daphnia magna: 10,800 mg/LSection 13: DISPOSAL CONSIDERATIONSDispose of in accordance with federal, state, and local regulations.Section 14: TRANSPORTATION INFORMATIONShipping Name: Consumer Commodity ORM-
23、DProper Shipping Name for Non-Consumer Commodity: Ethyl Alcohol Solutions, 3, UN1170, PGIII.Section 15: REGULATORY INFORMATIONEthyl alcohol, a component of this product, is on the TSCA inventory.California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65)This material contains e
24、thyl alcohol a developmental toxicity when in alcoholic beverages.Item Number: 152 Page06/10/2008 of 55The following components appear on one or more of the following state hazardous substancelists:ComponentCAS#CAMAMNNJPAEthyl alcohol64-17-5YESYesYesYesYesSection 16: Other InformationPrepared by: Vi
25、-Jon Inc.Disclaimer:The information and recommendations contained in the Material Safety Data Sheet (MSDS) aresupplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards HazardCommunication Rule. The information and recommendations set forth herein are presented ingood fait
26、h and believed to be correct as of this date hereof.Vi-Jon, however, makes no representation as to the completeness or accuracy thereof, andinformation is supplied upon the express condition that the persons receiving the information willbe required to make their own determination as to its suitabil
27、ity for their purposes prior to use. Inno event will Vi-Jon be responsible for any damages of any nature whatsoever resulting from theuse of, reliance upon, or the misuse of this information. User assumes all risk of use, storageand handling of the product in compliance with applicable federal, stat
28、e and local laws andregulations. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OFMERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY OTHERNATURE, ARE MADE BY VI-JON HEREUNDER WITH RESPECT TO INFORMATION OR THEPRODUCT TO WHICH THE INFORMATION REFERS. The information as suppl
29、ied herein issimply to be informative and intended solely to alert the user of the substance which is the subjectmatter of this MSDS. The ultimate compliance with federal, state or local regulations concerningthe use of this compound, or compliance with respect to product liability, rests solely upon thepurchaser thereof.This information relates to the material designated and may not be valid for such material used incombination with any other materials nor in any process.
