《三键取代的茂金属化合物作为反应物》由会员分享，可在线阅读，更多相关《三键取代的茂金属化合物作为反应物（400页珍藏版）》请在金锄头文库上搜索。
1、CHEMLIST, CHEMCATS: Copyright ?2009 American Chemical Society. All Rights Reserved.CASREACT: Copyright ?2009 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformation
2、s database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley 2009PPh2Ph2P+CCCAuFeCHCHCH CHCHCHC HC HC H-2+-S:CH2Cl2, 30 min, rtPhPhPhPhCCAuPPAuCCFeCCHCH CHCHCHCHC HC HC HCFeCHCH CHCHCHCHC HC HC H-+-2+-2+-93%NOTE: Reactants: 2, So
3、lvents: 1, Steps: 1, Stages: 1Answer 1:1 March 2010Page: 2SciFinder Scholar2 hit reactions in this referenceDalton Transactions, (38), 7885-7887; 2009+CFeCHCHCH CHCHCHC HC HCHR-2+-COCoCCCCoCHOOCCCOOOR00R:CO, S:Hexane, 45 h, 25COFeC CHCHCH CHCHCHC HC HCH2+-78%NOTE: Pauson-Khand reaction, Kodak Ektapr
4、o 3000 slide projector light source,photochemical, regioselective, Reactants: 2, Reagents: 1, Solvents: 1, Steps: 1, Stages: 11 March 2010Page: 3SciFinder ScholarAnswer 3:(Copyright (C) 2010 ACS. In addition to reactions indexed by CAS, CASREACT contains reactions derived from the following sources:
5、 ZIC/VINITI database (1974-1999) provided by InfoChem, INPI data prior to 1986, and Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich.)CASREACT1 March 2010Page: 4SciFinder Scholar(Copyright (C) 2010 ACS. In addition to reactions indexed by CAS, CASREACT contain
6、s reactions derived from the following sources: ZIC/VINITI database (1974-1999) provided by InfoChem, INPI data prior to 1986, and Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich.)CASREACT1 hit reaction in this referenceChemical Communications (Cambridge, Uni
7、ted Kingdom), (19), 2685-2687; 2009Pr-nn-PrMeMeMeMeMeMeMeMeOOOORhRhCH2C H2CCCCCSCCCCCS4+4+2-2-3 h, rtPr-nPr-nMeMeMeMeMeMeMeMeOOORhRhCCH2C H2C CCCSCCCCCSO-4+4+2-2-+Pr-nPr-nMeMeMeMeMeMeMeMeOOORhRhCCH2C H2C CCCSCCCCCSO-4+4+2-2-NOTE: photochem., solid-state, 100% overall yield, 300W Xe lamp used, mixtur
8、e of4 stereoisomers, Reactants: 1, Steps: 1, Stages: 11 March 2010Page: 5SciFinder ScholarAnswer 5:(Copyright (C) 2010 ACS. In addition to reactions indexed by CAS, CASREACT contains reactions derived from the following sources: ZIC/VINITI database (1974-1999) provided by InfoChem, INPI data prior t
9、o 1986, and Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich.)CASREACT1 hit reaction in this referenceZeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 63(12), 1395-1401; 2008NOI+CCNH2FeCCHCHCHCHCHCHC HC HCH2+-R:AcOH, S:AcOEt, S:AcOH, 4-6 h,
10、40 CICCNNFeC CHCHCH CHCHCHC HC HC H2+-32%NOTE: stereoselective, Reactants: 2, Reagents: 1, Solvents: 2, Steps: 1, Stages: 1Answer 4:1 March 2010Page: 6SciFinder ScholarAnswer 6:(Copyright (C) 2010 ACS. In addition to reactions indexed by CAS, CASREACT contains reactions derived from the following so
11、urces: ZIC/VINITI database (1974-1999) provided by InfoChem, INPI data prior to 1986, and Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich.)CASREACT1 hit reaction in this referenceJournal of the American Chemical Society, 131(34), 12112-12124; 2009CF3F3CSNHOOS
12、OO+CC CFeCHCHCHCHCHC HC HC HCHOO-2+-S:CH2Cl2, 10 min, rtOOCFeCHCHCH CHCHC HC HC HCH+-2+-CF3F3CSNOOSOO-82%NOTE: Reactants: 2, Solvents: 1, Steps: 1, Stages: 11 March 2010Page: 7SciFinder ScholarAnswer 7:(Copyright (C) 2010 ACS. In addition to reactions indexed by CAS, CASREACT contains reactions deri
13、ved from the following sources: ZIC/VINITI database (1974-1999) provided by InfoChem, INPI data prior to 1986, and Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich.)CASREACT1 hit reaction in this referenceMacromolecules (Washington, DC, United States), 42(16),
14、 5903-5905; 2009(CN)2C=C(CN)2+PhPhCCCFeCHCHCC HCHCH CHCHCHCC-2+-S:CH2Cl2, 2 h, 20CPhPhNCCNCNCNCCCCCCFeCCCHCHC HC HCH CHCHC H2+-100%NOTE: cyclobutene intermediate formed, Reactants: 2, Solvents: 1, Steps: 1, Stages: 11 March 2010Page: 8SciFinder ScholarAnswer 8:(Copyright (C) 2010 ACS. In addition to
15、 reactions indexed by CAS, CASREACT contains reactions derived from the following sources: ZIC/VINITI database (1974-1999) provided by InfoChem, INPI data prior to 1986, and Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich.)CASREACT9 hit reactions in this refe
16、renceEuropean Journal of Inorganic Chemistry, (25), 3911-3920; 2008MeMeOCC+MeCCCFeCHCHCH CHCHCHCHC HCH-2+-+ FOHReagent1.2 R:NaOH, S:H2O1.1 C:Mo(CO)6, S:PhMe, 5 h, rt 130 COMeCCCFeCHCHCH CHC HC HCHC HCH-2+-62%NOTE: microwave vial used, Reactants: 2, Reagents: 2, Catalysts: 1, Solvents: 2, Steps: 1, Stages: 21 March 2010Page: 9SciFinder ScholarAnswer 9:(Copyright (C) 2010 ACS. In addition to reactions indexed by CAS, CASREACT contains reactions derived fr
