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1、TABLE OF CONTENTSTABLE OF CONTENTSSEARCH TEXTSEARCH TEXTxviiV. LIST OF ABBREVIATIONS Abbreviation Chemical Name Chemical Structure 18-Cr-6 18-crown-6 OOOOOOAc acetyl Oacac acetylacetonyl OOAA asymmetric aminohydroxylation NA AD asymmetric dihydroxylation NAad adamantyl ADDP 1,1-(azodicarbonyl)dipipe
2、ridine NN N OO NADMET acyclic diene metathesis polymerization NAacaen N,N-bis(1-methyl-3-oxobutylidene)ethylenediamine NNOOAIBN 2,2-azo bisisobutyronitrile NNNNAlloc allyloxycarbonyl OOAm amyl (n-pentyl) An p-anisyl OANRORC anionic ring-opening ring-closing NA aq aqueous NAAQN anthraquinone OOAr ary
3、l (substituted aromatic ring) NATABLE OF CONTENTSTABLE OF CONTENTSSEARCH TEXTSEARCH TEXTxviiiAbbreviation Chemical Name Chemical Structure ATD aluminum tris(2,6-di-tert-butyl-4-methylphenoxide) OAl3 atm1 atmosphere = 105 Pa (pressure) NAATPH aluminum tris(2,6-diphenylphenoxide) OPhPhAl3BBN (9-BBN) 9
4、-borabicyclo3.3.1nonane (9-BBN) BHB9-borabicyclo3.3.1nonyl BBCMEbis(chloromethyl)ether OClClBCNN-benzyloxycarbonyloxy-5-norbornene-2,3- dicarboximide ONOOOOBDPP(2R, 4R) or (2S, 4S) bis(diphenylphosphino)pentane (R)(R)Ph2PPPh2BERborohydride exchange resin NABHT2,6-di-t-butyl-p-cresol (butylated hydro
5、xytoluene) OHBICP2(R)-2(R)-bis(dipenylphosphino)-1(R),1(R)- dicyclopentane (R)(R)(R)(R) Ph2PPPh2BINAL-H 2,2-dihydroxy-1,1-binaphthyl lithium aluminum hydrideOOAl HH LiBINAP 2,2-bis(diphenylphosphino)-1,1-binaphthyl PPh2PPh2TABLE OF CONTENTSTABLE OF CONTENTSSEARCH TEXTSEARCH TEXTxixAbbreviation Chemi
6、cal Name Chemical Structure BINOL1,1-bi-2,2-naphtholOHOHBipbiphenyl-4-sulfonyl SOObipy 2,2-bipyridyl NNBLA Brnsted acid assisted chiral Lewis acid NAbmin1-butyl-3-methylimidazolium cation NNBMSBorane-dimethyl sulfide complex H3BSMe2Bnbenzyl BNAH 1-benzyl-1,4-dihydronicotinamide NONH2BOB4-benzyloxybu
7、tyryl OOBoct-butoxycarbonyl OOBOMbenzyloxymethyl OBOP-Clbis(2-oxo-3-oxazolidinyl)phosphinic chloride POClONOONObpboiling point NABPDbis(pinacolato)diboron OOBBOOBPObenzoyl peroxide OOPhOPhOBPS (TBDPS) t-butyldiphenylsilyl SiTABLE OF CONTENTSTABLE OF CONTENTSSEARCH TEXTSEARCH TEXTxxAbbreviation Chemi
8、cal Name Chemical Structure BQbenzoquinone OOBsbrosyl = (4-bromobenzenesulfonyl) SBrOOBSA N,O-bis(trimethylsilyl)acetamide O NSiSiBSA Bovine serum albumin NABt1- or 2-benzotriazolyl N N NBTAF benzyltrimethylammonium fluoride NFBTEA benzyltriethylammonium NBTEAC benzyltriethylammonium chloride NClBTF
9、P3-bromo-1,1,1-trifluoro-propan-2-one OFFF BrBTMA benzyltrimethylammonium NBTMSA bis(trimethylsilyl) acetylene SiSiBTSbis(trimethylsilyl) sulfate S OOOOSiSiBTSA benzothiazole 2-sulfonic acid SNSOOHOBTSPbis(trimethylsilyl) peroxide OOSiSiBzbenzoyl OBu (nBu)n-butyl ccyclo NATABLE OF CONTENTSTABLE OF C
10、ONTENTSSEARCH TEXTSEARCH TEXTxxiAbbreviation Chemical Name Chemical Structure cacirca (approximately) NACA chloroacetyl OClCAN cerium(IV) ammonium nitrate (cericammonium nitrate)Ce(NH4)2(NO3)6cat.catalytic NACBcatecholborane OHBOCBSCorey-Bakshi-Shibata reagent NBOHPh PhRR = H, alkylCbz (Z) benzyloxy
11、carbonyl OOcc. or conc. concentrated NA CCEconstant current electrolysis NACDIcarbonyl diimidazole ONNNNCHD1,3 or 1,4-cyclohexadiene 1,3-CHD1,4-CHDCHIRAPHOS 2,3-bis(diphenylphosphino)butane (S)(S)PPhPhP PhPhChx (Cy) cyclohexyl CIP2-chloro-1,3-dimethylimidazolidinium hexafluorophosphate NHNClPF6CM (X
12、MET) cross metathesis NACMMPcyanomethylenetrimethyl phosphorane PNCOD1,5-cyclooctadiene COT1,3,5-cyclooctatriene Cpcyclopentadienyl CPTScollidinium-p-toluenesulfonate NHSOOOTABLE OF CONTENTSTABLE OF CONTENTSSEARCH TEXTSEARCH TEXTxxiiAbbreviation Chemical Name Chemical Structure CRA complex reducing
13、agent NACr-PILCchromium-pillared clay catalyst NACSA camphorsufonic acid OSO3HCSIchlorosulfonyl isocyanate ClSOONCOCTAB cetyl trimethylammonium bromide NBrCTACl cetyl trimethylammonium chloride NC15H31ClCTAP cetyl trimethylammonium permanganate NC15H31MnO4 heatNAddays (length of reaction time) NADAB
14、CO 1,4-diazabicyclo2.2.2octane NNNNDAST diethylaminosulfur trifluoride SNFFFDATMP diethylaluminum 2,2,6,6-tetramethylpiperidide NAlEt2DBA (dba) dibenzylideneacetone OPhPhDBAD di-tert-butylazodicarboxylate N NOOOODBIdibromoisocyanuric acid NONONHOBrBrTABLE OF CONTENTSTABLE OF CONTENTSSEARCH TEXTSEARC
15、H TEXTxxiiiAbbreviation Chemical Name Chemical Structure DBMdibenzoylmethane OODBN1,5-diazabicyclo4.3.0non-5-ene NN12 3456789DBSdibenzosuberyl DBU1,8-diazabicyclo5.4.0undec-7-ene NN12345 67 891011DCA 9,10-dicyanoanthracene CNCNDCB1,2-dichlorobenzene ClClDCCdicyclohexylcarbodiimide NCNDCE1,1-dichloro
16、ethane ClClDCMdichloromethane CH2Cl2DCN1,4-dicyanonaphthalene CNCNDcpmdicyclopropylmethyl DCUN,N-dicyclohexylurea NHONHDDQ2,3-dichloro-5,6-dicyano-1,4-benzoquinone OONCNCClClde diastereomeric excess NATABLE OF CONTENTSTABLE OF CONTENTSSEARCH TEXTSEARCH TEXTxxivAbbreviation Chemical Name Chemical Structure DEAD diethyl azodicarboxylate NNOOOODEIPSdiethylisopropylsilyl SiDEPBT3-(diethoxyphosphoryloxy)-1,2,3-benzotriazin- 4(3H)-oneNNNOOPOEt EtOODETdiethyl tartra
