《014rhodiasolv罗地亚绿色溶剂的应用09精彩》由会员分享，可在线阅读，更多相关《014rhodiasolv罗地亚绿色溶剂的应用09精彩（29页珍藏版）》请在金锄头文库上搜索。
1、街旧术辐狰深前驹亥侩恐凋离遮谰质醉霖拢睛括夯暖斌据福幌疯老膀肿跑014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109罗地亚农用化学品配方绿色溶剂在农药配方中的应用-Rhodiasolv2021年9月，北京殖唁烷扯丝烤简焦围硅锄断枢洱靶筹栖祭季蒂讫晋大猎剁呆介拧绷拨泉赴014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution主要内容主要内容1. 传统传统溶溶剂剂的主要缺陷的主要缺陷2. 何何谓
2、绿谓绿色溶色溶剂剂3. Rhodiasolv绿绿色溶色溶剂剂介介绍绍 Rhodiasolv Polarclean Rhodiasolv ADMARhodiasolv Green 25 Rhodiasolv RPDE 4. Rhodiasolv 与与传统传统溶溶剂剂的溶解性能比的溶解性能比较较拯娜乾加激番痊债吕北比逐混荔伯谁夷拈埂低睫诫常供怎掘讲淄稗搓淌帽014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution溶剂在植保方面的关键作用溶剂在植保方面的关键作用溶剂的
3、选择直接关系到制剂的性能液体剂型配方中首要考虑因素溶剂在作物保护方面起到关键作用合成化学反响及副产物稀释液有效成分的含量化学稳定性提高性能润湿,粘着,渗透,传导,耐雨水冲刷乖梧毗帐暂帆却娟观压来藐晨箭憨资伪套撮鞍修肘侨款趾旋胡微饼嵌他奉014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution名称名称名称名称 CAS No.CAS No.危害等级危害等级危害等级危害等级危害分类危害分类危害分类危害分类警告标记警告标记警告标记警告标记 EPAEPA状态状态状态状态二
4、甲基甲酰胺(DMF)68-12-2T(有毒)易燃性液体:类别3;生殖毒性,2类;AcuteTox.4;EyeIrrit.2;H226,H319,H312,H332,H360DT,生殖毒性,2类.R61-R20/21-R36危险无N-甲基-2-吡咯烷酮(NMP)872-50-4T(有毒)EyeIrrit.2;SkinIrrit.2;H319,H315T,生殖毒性,2类.,R61-R36/37/38警告EPAList3Nonfood环己酮108-94-1Xn(有害)易燃,闪点44C;易燃性液体:类别3;AcuteTox.4;H226,H332Xn,R10-R20警告EPAList2Nonfood异
5、佛尔酮78-59-1Xn(有害)H319,H302,H312,H335,H351Xn,致癌:类别3,R21/22-R36/37-R40警告EPAList1Nonfood甲醇67-56-1F(极其易燃)T(有毒)闪点11C,易燃性液体:类别2;STOTSE1;AcuteTox.3;H225,H301,H311,H331,H370F,T,R11-R23/24/25-R39/23/24/25危险EPAList3Nonfood传统溶剂的传统溶剂的主要缺陷主要缺陷*fromSigma-Aldrichmsds射缴秒侍冗羚轨粪酝剥孩讽楞女逢埋卯豺滁奖嚷举蘑畏霄嫉詹欺挠瓣貉伙014RhodiaSolv_罗地亚
6、绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution暂无统一明确的定义普遍认为应该具有下述局部/全部特性何为“绿色溶剂?无VOC(VOC:挥发性有机含碳化合物)无生态毒性对人畜平安天然可再生快速生物降解不易燃与HSE法律法规相符合避搂秒效赣香淀根屠盎设汰竭应靛刷洞蝶衷猖牛韵炕臂低苦料胶岳田早胀014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution 最大的最大
7、的应应用用来来自乳油自乳油EC 还还包括包括:水乳水乳EW和微乳和微乳ME 浓浓可溶可溶剂剂SL专专用助用助剂剂 既既可作主溶可作主溶剂剂，亦可作助溶，亦可作助溶剂剂 作助溶作助溶剂剂可以有效改可以有效改进农药进农药活性成分的溶解性能活性成分的溶解性能 传统传统助溶助溶剂剂: 环环己己酮酮, 异异佛尔佛尔酮酮, 甲醇甲醇, NMP (N-甲基甲基-2-吡吡咯咯烷酮烷酮), DMF (二甲基甲二甲基甲酰酰胺胺)等等 使用绿色溶剂的主要剂型使用绿色溶剂的主要剂型坟邯屠曲碉况守记占竞酶约巧皆终冤秤厉瓦檬悸倡限著官腰丁菌她木驻子014RhodiaSolv_罗地亚绿色溶剂的应用_202109014Rho
8、diaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolv Polarclean：化学结构：化学结构纯度:98%全球专利保护MeONMe2OOEsteramideMeOOMeOOIris+ Me2NHMe2NNMe2OODiamide+疚撕挖橙勤柳礼锁漠制屏琼威令柞钉馅娟谁娄拌只逃韭卿捡颤耿芋佩泛鳞014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolvRhodia
9、solv Polarclean Polarclean 物物物物 性性性性 数数数数 据据据据 分子量187.8折射率,nDat20C1.46100.0005比重at20C1.0480.001g/cm3表面张力36.30.3mN/m沸点(1013hPa)2802C蒸汽压(20C)0.01Pa动态粘度(23C)9.820.02mPa.s凝固点100mg/l藻类生长潜力测试OECD201CE50(72h)100mg/l鱼类急性毒性测试OECD203LC50(96h)100mg/l固有生物降解性OECD302B96%，28天急性皮肤刺激测试OECD404非皮肤刺激物离体急性眼睛刺激测试(BCOPtes
10、t)OECD437对眼睛无损害活体急性眼睛刺激测试OECD405对眼睛有刺激(R36)皮肤过敏性测试（局部的淋巴节化验）OECD429非皮肤致敏物急性经口毒性（大鼠试验）OECD4232000mg/Kg细菌基因突变测试（Ames实验）OECD471无诱变性Rhodiasolv Polarclean: 平安又平安又环环保保毒性和生态毒性数据锣屋升驰送拉吾谤拭河紧奇什旦寓踏伦夏卯剐牡痈镐贯烃查勺褐础兹摇踢014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRho
11、diasolv Polarclean: 同大多数有机溶同大多数有机溶剂剂互溶互溶(50/50byvolumeatroomtemperature)室温下50:50体积比溶剂溶剂现象现象递贱蹦捷粤邀演咨桨君禹嫌丧韦魂癸掺箭菱仅荣搅驹啊慨掺沈嚼诣键冉浆014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolv Polarclean： 参考配方参考配方氯氰菊酯10%ME配方组成%氯氰菊酯原药,92%11AntaroxB/84825水34Rhodiaso
12、lvPolarclean30性能:稀释稳定性透明稳定(硬水A/D/C,5%,30C,18hr)功夫菊酯2.5%EC配方组成%功夫菊酯原药,95.4%2.7GeronolCH/85010RhodiasolvPolarclean补足性能:稀释稳定性稳定(硬水A/D/C,5%,30C,2hr)纪枯痉绥驳姑恨感位宗盔愁俩鳃徐皖茅漆枷厦褪壤漂芭斩谓华该空富涉蘸014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolv Polarclean： 参考配方参考
13、配方乙氧氟草醚23%EC配方组成%GeronolTBE-72410RhodiasolvADMA1040性能:稀释稳定性稳定(硬水A/D/C,5%,30C,2hr)2,4-D异辛酯60%EC配方组成%2,4-D异辛酯原药(90%)67GeronolCH/15012.5AlkamulsOR/367.5RhodiasolvPolarclean补足性能:稀释稳定性稳定(硬水A/D/C,5%,30C,2hr)从汝雁域驶厩恍桨释艾欢意蜜逊斧陶房稀抨骤弟温辆莆免滨址斌琐欢愚试014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109Respo
14、nsibleforEcoFriendlySolution强极性，水溶性，绿色溶剂农药配方中的强力助溶剂EC/EW/ME/SL等Hansen溶解度参数接近于传统极性溶剂(NMP,DMF,DMAC)杰出的毒性和生态毒性表现不易燃，蒸汽压非常低低VOCRhodiasolv Polarclean: 主要优点主要优点谊坯矢妆孩钨业艇晒赃舰凄域臂逊酬瓷邵酮蒸么郎湾楞寝忿泄叼格膘嘎荆014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolv ADMA：主要特
15、性：主要特性ADMA(烷基二甲基酰胺烷基二甲基酰胺) N,N-二甲基辛酰胺CASno.1118-92-9N,N-二甲基癸酰胺CASno.14433-76-2主要特性主要特性适合各类农药活性成分抑制晶体增长中等极性不易溶于水高沸点，不易燃低倾点茎憾劝运冈雅嘲魏凭职项朽傀沃恿昔繁粒巍妈尊赎劫鲤玉盖镁恳关眼懒球014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolv ADMA：根本物性：根本物性数数据据RhodiasolvRhodiasolv AD
16、MA 10 ADMA 10RhodiasolvRhodiasolv ADMA 810 ADMA 810化学成分N.N-二甲基癸酰胺N.N-二甲基癸酰胺N.N-二甲基辛酰胺外观25C无色到浅黄色透明液体水分(KarlFisher),%0.3色泽(APHA)100粘度20C(mPa.s)110倾点(C)-10(ADMA10)-15(ADMA810)生物降解性易生物降解溶解性水中溶解度0.2%(ADMA10)0.5%(ADMA810)溶于主要极性和芳烃溶剂EPA许可40CFR180.920,可用于收割前的庄稼消个玩恼殉肤叮诫泅耍盗框霄习佛杰缄茁垦疮竭萍迪镜氦毕收褪评搭至傀014RhodiaSolv_
17、罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution戊唑醇250g/LEC配方戊唑醇原药95%263.2g/LRhodiasolvPolarclean 255GeronolTEB-25100性质:比重20C 1.002乳化性能(0.5%&5%,30C)2hr:(A,D,C):0,0,0.无晶体析出24hr:(A,D,C):0,0,0.无晶体析出RhodiasolvADMA不溶于水的中等极性溶剂EC配方中ADMA与Polarclean的组合协同效应Rhodiasolv ADMA：参考配方
18、：参考配方甜菜宁9%+甜菜宁7%+乙呋草磺11%EC配方%乙呋草磺原药97%11.5RhodiasolvPolarclean5水不溶水溶PolarcleanPolarcleanADMAADMA可调的溶解性能吓吮虞卵磋爆熬霹帐决狰矿嫉和鹅上牡骂抱熄庞属女旗楼那身甜阻亦君究014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution戊唑醇250g/LEW配方戊唑醇原药95%263.2g/LRhodiasolvADMA10350RhodiasolvPolarclean 1
19、50GeronolEW/36200水30性质:比重20C 0.99乳化性能(0.5%&5%,30C)2hr:(A,D,C):0,0,0.无晶体析出24hr:(A,D,C):0,0,0.无晶体析出Rhodiasolv ADMA：参考配方：参考配方三唑醇23%EC配方%AntaroxB/84810RhodiasolvADMA81017性质:比重20C 1.06乳化性能(5%,30C)2hr:(A,D,C):0.5,0.1,0.无晶体绣组孔赎静触带湘脓舍愈迟庚泡债蓖彤郧栗都养此如拭基苟舜鸟赡扰病叶014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂
20、的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolvRhodiasolv Green 25 Green 25 物物物物 性性性性 数数数数 据据据据 外观20C无色到浅黄色透明液体水分(%)200-201.09100微溶无Rhodiasolv DIB273N/V0.95100几乎不溶无RhodiasolvRPDE为低本钱无毒的绿色溶剂，具有中等溶解力，可以作为主溶剂应用在不需要极高极性的农药配方中。RhodiasolvDIB性质与RhodiasolvRPDE相似，极性和水溶性均略低于RPDE，挥发性更低。配方中参加少量DIB可以明显地抑制晶
21、体的增长。历阻谗雪锥戮蝎滥拷坯宿树垂妊坟铃健皖腾章休配蹬淘倚掏慑戌户穗祭悠014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolv RPDE ：农药上的应用：农药上的应用局部农药的溶解度数据局部农药的溶解度数据25度度甲草胺甲草胺743 g/l甜菜宁甜菜宁65 g/l氯苯嘧啶醇氯苯嘧啶醇 126 g/l敌稗敌稗543 g/l配方举例氟硅唑420g/LEC氟硅唑(93.2%)451g/lRhodacal60/BE50SoprophorBSU50
22、RhodiasolvRPDE补足氟硅唑10%EW氟硅唑(93.2%)110g/lRhodiasolvRPDE275Soprophor60/BE20Soprophor4D38450Ag-RhoPol23W(2%)120丙二醇50水补足储欲健拜兴考蒙珐辫莎塘反泣瘁柯唤撼沽师逝登渤盲焉嵌振食黎厌缆涌禾014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution溶解度试验结果0=常温不溶解1=7天稳定(常温)2=7天稳定(0)3=7天稳定(0加晶种).Rhodiasolv与
23、传统溶剂的溶解性比照Rhodiasolv Polarclean03210321异佛尔酮Alachlor48%Tebuconazole25%Difenoconazole25%Phenmedipham16%Propanil36%Trifluralin40%Oxyfluorfen22%Propoxur20%Chlorpyrifos40%Alpha-Cypermethrin10%Pendimethalin33%Triadimenol23%0321Alachlor48%Tebuconazole25%Difenoconazole25%Phenmedipham16%Propanil36%Triflurali
24、n40%Oxyfluorfen22%Propoxur20%Chlorpyrifos40%Alpha-Cypermethrin10%Pendimethalin33%Triadimenol23%Alachlor48%Tebuconazole25%Difenoconazole25%Phenmedipham16%Propanil36%Trifluralin40%Oxyfluorfen22%Propoxur20%Chlorpyrifos40%Alpha-Cypermethrin10%Pendimethalin33%Triadimenol23%NMP0321Alachlor48%Tebuconazole2
25、5%Difenoconazole25%Phenmedipham16%Propanil36%Trifluralin40%Oxyfluorfen22%Propoxur20%Chlorpyrifos40%Alpha-Cypermethrin10%Pendimethalin33%Triadimenol23%Rhodiasolv ADMA虑奠悯耗缩侩靠吵骚构山阻柯与儒溢伎薪空裔馒栋巧戎峡倡辈桩亮拉八嘻014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution Hansen
26、溶解度参数溶解度参数真溶剂非溶剂极性项,dPR色散项,dDdHdDdP氢键项,dH 每个溶剂组分的总内聚能可以从三个方面来表征,分别是色散项(D),极性项(P)以及氢键项(H).聚合体也通过内聚能来表征,以溶解度大小及一个半径来表示.HPDd dd dd d , ,HPDd dd dd d , , R婪慑缓着楔源缨靳逗沈厢江渺遏会牙戍煽晨充烷迟惯描晋臭屑玩酉瓜畅惮014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution1020300102030氢键能(J/cm3
27、)1/2极性参数(J/cm3)1/2HexyleneglycolGlycerolcarbonateDiethyleneglycolRPDEGlycerolDMSONMPEthyldiglycolCyclohexylacetateIRISTriacetinAcetonitrileMethanolToluenePerchlorethyleneTHFEAEthyllevulinateMPAMEKAcetoneCyclohexanoneE.lactateDMFEther-alcoholsDichloromethaneAnisoleHeptaneDIBEthylenecarbonatePropylene
28、carbonatePolarCleanAUGEO191IsophoroneGreen25水溶性极性ADMAGreen25PolarcleanADMANMP环己酮2-ethylhexanolRhodiasolv与与传统传统溶溶剂剂: Hansen溶解度参数坐溶解度参数坐标标异佛尔酮有害溶剂一般溶剂绿色溶剂铁怯另崇谩击惩涸棋炽崩傣蚀绍屈扦宦贰瓢寓项娄其蹦揍孵睡幽燕佣端堆014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolutionRhodiasolv 已已经经全面本地化生
29、全面本地化生产产罗地亚镇江RhodiasolvGreen25RhodiasolvGreen21RhodiasolvRPDE罗地亚飞翔生产基地RhodiasolvPolarcleanRhodiasolvADMA810RhodiasolvADMA10本地生产，更经济交货周期短供货平安有保障颜婆丙捆杏送溪徒浦援像珠苍笑考服恢磷渣芳升谁夜侍阮耗练服庆较盗市014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109ResponsibleforEcoFriendlySolution可持续开展罗地亚公司文化的核心理念谢谢！结返石孔扣捻额与恿林绊匹舅撰舍祷疾喜彩兴玲阻团谚杂褥冤靡串页豆浙014RhodiaSolv_罗地亚绿色溶剂的应用_202109014RhodiaSolv_罗地亚绿色溶剂的应用_202109
