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1、State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室Lecture 8State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大
2、学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物12.1 IntroductionSo far most of the compounds we have studied have been open-chain compounds. We also discussed a few ring compounds, the cycloalkanes and cycloalkenes, and found their properties to be very much like
3、their counterparts, the alkanes and alkenes.Open-chain compounds and their corresponding ring compounds are known as aliphatic (脂肪族的）脂肪族的）compounds.The term aliphatic comes from the Greek word aleiphar, which means “oil”.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验
4、室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物In this chapter, we will introduce another class of organic compounds called the aromatics（芳香族）. Benzene(苯) and its derivatives were originally called aromatic compounds because of their rather pleasant aromas. The term aromatic now
5、 refers to any compound which has a benzene ring in its structure or has chemical properties similar to those of benzene. In the sections that follow, we will describe the structure and the properties of benzene and many of its derivatives.State Key Laboratory for Physical Chemistry of Solid Surface
6、s厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物In the 1820s, a pure liquid hydrocarbon called benzene was first isolated. Chemists found that the molecular formula of this new substance was C6H6, but it took some time for them to figure out a structure which w
7、as consistent with the properties of benzene.Open-chain structures, such as CH2=CH-CC-CH=CH2, were first proposed, but it is inconsistent with the chemical property that benzene undergoes substitution with bromine, instead of the addition reaction with bromine(溴).State Key Laboratory for Physical Ch
8、emistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物The chemist August Kekul(1829-1896) proposed an alternative structure in which the six carbon atoms of benzene are joined together to form a hexagon with each ring C atom bonded to an H ato
9、m.The inspiration for this idea supposedly sprang from a daydream in which Kekul visualized “long rows , all twining and twisting in snakelike motion,” and then saw that “One of the snakes had seized hold of its own tail”. In any case, Kekuls structure turned out to be correct. Benzene is a ring com
10、pound. State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物However, this structure also failed to answer many questions about the properties of benzene. If the structure above were correct, benzene would s
11、till be expected to be highly reactive because of the three double bonds it contains. Furthermore, if the benzene ring really did have alternating single and double bonds, the distance between doubly bonded C atoms would be shorter than that between singly bonded C atoms, yet all physical measuremen
12、ts showed that the six C to C bond distances were identical. State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物There are three atoms attached to each C atom in benzene. Each C atom has three sp2 hybrid o
13、rbitals, with which the s s framework of benzene bonding is established.Each C atom has one unhybridized p orbital containing one electron. These overlapping p orbitals form a continuous p p bond about the benzene ring.The p p electrons are not localized between any two carbon atoms. Rather, all six
14、 p p electrons are delocalized over the entire ring.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物Benzene bonding: a) s s framwork; b) continuous p p bond.State Key Laboratory for Physical Chemistry
15、of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物The drawing we use to represent the structure of benzene is a hexagon with a circle inside it. The circle represents the continuous p p bonding about the benzene ring. Another commonly encountered
16、depiction of benzene is the following:State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物The compounds that form when one or more H atoms of benzene are substituted with other atoms or groups of atoms are
17、 named as derivatives of benzene.In monosubstituted benzenes one H atom is replaced by another atom or group X. To name such compounds, the name of the substituent X is followed by the word benzene. For instance, if a chlorine atom is the substituent, the compound is called chlorobenzene and if the
18、attached group is nitro(-NO2), the name of the compound is nitrobenzene.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物Disubstituted benzenes: There are three different ways to place two substituents
19、on a benzene ring.Number the position of the benzene ring so that the substituents are on the positions with the lowest possible numbers. The number 1 is assigned to the substituent that is lower in alphabetical order. State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采
20、用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物Halogenation: Benzene reacts with bromine or chorine to form bromobenzene or chlorobenz
21、ene in the present of an iron catalyst (Fe, Fe Br3 or FeCl3). Nitration: Nitrobenzene can be prepared by reacting with nitric acid in the presence of sulfuric acid.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，
22、保持熔接部位干净无污物Hydrocarbons such as alkylbenzenes toluene and ethylbenzene, which have both aliphatic and aromatic components, are called arenes.Because arenes have both aromatic and aliphatic character, they also have properties of aliphatic as well as of aromatic compounds.Benzene itself is more toxic
23、 than any of the arenes. The reason for this is related to the inertness of benzene, which makes it difficult for the body to eliminate it.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物A fused-ring a
24、romatic is a compound that forms when two or more aromatic rings are joined at two or more C atoms. The source of fused-ring aromatics is a substance called coal tar(焦油焦油), the liquid residue produced when coal is heated in the absence of air. State Key Laboratory for Physical Chemistry of Solid Sur
25、faces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物13.1 IntroductionIn the next few chapters we will introduce the organic compounds which have oxygen atoms in their functional groups. Two of these are alcohols and ethers.We can produce the structures of both
26、classes of compounds starting with a water molecule, HOH. By replacing one of the H atoms in water with a C atom, we have the general formula of an alcohol, written ROH, where R refers to a hydrocarbon group.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给
27、水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物For instance, if the R is a methyl group, the alcohol formula is CH3OH (methanol), and when R is a phenyl group, the alcohol is phenol. To produce the ether structure, both H atoms of water are replaced with hydrocarbon groups. We write the gene
28、ral formula with an R and R (R prime), meaning that the attached hydrocarbon groups can be the same or different. General ether formula: R-O-RState Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物Alkyl alcoh
29、ols can be named as alkanols, a name derived by dropping the e from alkane and adding ol. For instance, the name of the alcohol derived from the simplest alkane comes from changing the methane to methanol (CH3OH). Ethanol is a two-carbon alcohol: CH3CH2OH.To name any alcohol more complex than these,
30、 we must indicate the location of the OH group as well as those of any other branch groups. To do this we follow the rules below.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物Rule 1: Choose the longe
31、st C to C chain to which the OH group is attached. This gives the parent alcohol name.Rule 2: Number the C atoms so that the C atom bonded to the OH group has the lowest possible number.Rule 3: Form the name by placing the number of the C atom to which the OH is attached in front of the parent alcoh
32、ol. Indicate any branched groups according to the rules of alkane nomenclature.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物The parent name of this alcohol must be hexanol.Numbering the C chain.This
33、 hexanol is a 2-hexanol.The full name of this hexanol is 5-methyl-2-hexanol.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物Alkyl alcohols can be divided into one of the three classes( primary, seconda
34、ry or tertiary), depending on the type of C atom to which their hydroxyl groups are attached.In primary alcohols the hydroxyl group is attached to a primary C atom, that is, a carbon atom that is bonded to only one other C atom, e.g., CH3CH2OH.State Key Laboratory for Physical Chemistry of Solid Sur
35、faces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物In secondary alcohols, the hydroxyl group is attached to a secondary C atom, that is, a carbon atom that is bonded to two other C atoms. The following alcohols are thus secondary alcohols.In tertiary alcohols,
36、 the OH group is attached to a tertiary C atom, a C atom which forms bonds with three other C atoms.State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物Ethers are named by giving the names of R and R hydro
37、carbon groups in the general formula ROR, in alphabetical order, followed by the word ether.When R and R are the same, the name of the R groups is given only once or the prefix di- is used in the name.Using this method we can name the ethers below:CH3CH2OCH2CH3 (diethyl ether) CH3OCH2CH3(Ethyl methyl ether)State Key Laboratory for Physical Chemistry of Solid Surfaces厦门大学固体表面物理化学国家重点实验室采用PP管及配件：根据给水设计图配置好PP管及配件，用管件在管材垂直角切断管材，边剪边旋转，以保证切口面的圆度，保持熔接部位干净无污物See you next week!Have a nice day!Assignment: Write an article (about 200 words) with the title Aromatics: Pleasant or dangerous?.
