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1、TheLubrizolCorporation2006,allrightsreservedMetalworkingAdditives金属加工添加剂金属加工添加剂October2012TheLubrizolCorporation2007,allrightsreservedAgenda议程Introduction概况介绍MetalworkingCapabilitiesandSupport金属加工系列产品线和技术支持ProductOfferingandFormulationAdvices产品介绍和配方举例Questions问题2TheLubrizolCorporation2007,allrightsr
2、eservedSulfurizedEPAdditives,TraditionalSolubleOilEmulsifier硫系极压剂及乳化剂产品硫系极压剂及乳化剂产品WaterbasedAdditives,EmulsifierExpertise,SpecialityPolymericEsters水基添加剂、乳化剂和聚合酯水基添加剂、乳化剂和聚合酯WaterbasedAdditives,CorrosionInhibitorExpertise,水基防锈及防腐水基防锈及防腐蚀剂蚀剂Biocides杀菌剂杀菌剂RustPreventives,WaterbasedCorrosionInhibitors防锈
3、剂防锈剂RustPreventives,NaturalSulfonatesupply,ThixotropicGelledSulfonate防锈剂、磺酸盐防锈剂、磺酸盐3TheLubrizolCorporation2007,allrightsreservedGlobalSupport全球技术支持Technicallaboratories技术实验室Wickliffe,OHUSABrecksville,OHUSAHazelwood,EnglandSpartanburg,SCUSAMetalworkingResearch&TechnicalService金属加工产品研发和技术支持金属加工产品研发和技术
4、支持Hamburg,Germany德国汉堡德国汉堡MetalworkingTechnicalSupport金属加工产品技术支持金属加工产品技术支持Shanghai,China上海上海MetalworkingTechnicalSupport金属加工产品技术支持金属加工产品技术支持4TheLubrizolCorporation2007,allrightsreservedShanghaiMetalworkingResources上海实验室配置和评价方法ProcedurePropertyEvaluatedIP287FilterPaperChipBreakpoint防锈/滤纸铁屑法IP263Emulsi
5、onStability乳化安定性IP311ConcentrateStorageStability储存稳定性IP312FoamTestShakingMethod泡沫试验ASTMD455KineticViscosity黏度测定LubrizolPumpTestFoamTest路博润泡沫试验MicroTapIILubricity润滑性评定/攻丝扭矩Mod.TimkenFishTank BacteriaResistance抗菌性试验Ifneedtechnicalserviceforourcustomers,plsfillinTSRsfirst.MicroTapFoamRig5TheLubrizolCor
6、poration2007,allrightsreservedAdditivesApplicationsCapabilities路博润添加剂的应用领域Cleaners清洗剂清洗剂MetalRemoval切削切削MetalForming成型成型ProcessAdditives工艺助剂工艺助剂RustPreventives防锈防锈IndustrialAdditives工业用油工业用油CorrosionInhibitors腐蚀抑制腐蚀抑制InternalLubrication润滑润滑LubrizolMetalworkingAdditives6TheLubrizolCorporation2006,all
7、rightsreservedMetalworkingAdditivesProductOfferingforWaterbasedProducts水基金属加工液产品介绍水基金属加工液产品介绍TheLubrizolCorporation2007,allrightsreservedMetalworkingAdditives金属加工添加剂WaterBasedWaterMiscible水基或水溶性产品-AqueousFluidSystem应用于水基体系-GenerallySuppliedasConcentrateforDilutioninWater通常以浓缩液的形态供应，使用时以水稀释-SubCatego
8、ries这类产品包括SolubleOil乳化油Synthetic全合成液SemiSynthetic半合成液8TheLubrizolCorporation2007,allrightsreservedProductCategories产品EmulsifierComponentsEmulsifierPackagesHongJing乳化复合剂洪泾介绍ExtremePressureAdditivesLubricityAdditives润滑剂RustPreventivesCorrosionInhibitors防锈剂IndustrialMetalworkingBiocides杀菌剂9TheLubrizolC
9、orporation2007,allrightsreservedLubricityAdditivesforwatermisciblefluids水基润滑剂水基润滑剂10TheLubrizolCorporation2007,allrightsreservedLubricity/EPagents润滑/极压剂ADDOSANESTEP206TMP-EsterofCastoroilandOleicacid是以蓖麻油和油酸为原料的TMP的酯AddosanESTEP206isusedasanEP-additiveinwatermisciblemetalworkingfluids,especiallyforA
10、l-processing.Typicaltreatlevelsintheconcentrateshouldbe5-10%.该产品可用于水基配方中做极压剂，特别适合铝加工。加量该产品可用于水基配方中做极压剂，特别适合铝加工。加量510%Forthemachiningofsteeltheadditionshouldbebetween5and20%totheconcentrate,dependingontherequirementsandtheseverityoftheprocess用于钢材加工时需要在浓缩液里加入用于钢材加工时需要在浓缩液里加入520%，视加工的剧烈程度而定。，视加工的剧烈程度而定
11、。Innonwaterbasedmetalworkingfluids,AddosanESTEP206isqualifiedforfinesteelwiredrawingincombinationwithP-EPandS-additives.在非水基的体系中它与含磷或含硫极压剂共用可用于细钢线的拉拔。在非水基的体系中它与含磷或含硫极压剂共用可用于细钢线的拉拔。AddosanESTEP206canalsobeusedasafattyagentinnon-watermisciblemetalworkingfluids.在非水溶性配方里可用作油性剂在非水溶性配方里可用作油性剂Itisalsosuita
12、bleforgrindingprocesseswhereagoodstabilityofthefattycomponentisrequired.在磨削加工中如果需要使用稳定性好的油性剂，可考虑使用该产品在磨削加工中如果需要使用稳定性好的油性剂，可考虑使用该产品11TheLubrizolCorporation2007,allrightsreservedAddosanEstep206PropertiesColour颜色:ligthbrown浅棕色Acidvalue酸值(mgKOH/g):max10Viscosity黏度(40C):appr85mm/sTypicaluselevel典型用量Water
13、based水基:510%Neatoils油基:12%(neatoils:2%Estep206+0.5%EPC127-usedforflutegrinding在油基配方中使用2%Estep206+0.5%EPC127可用于成管加工)12TheLubrizolCorporation2007,allrightsreservedBECROSANE2135amineandboronfreeformulationwithbiocide配方举例：不含胺、不含硼的半合成液配方配方举例：不含胺、不含硼的半合成液配方BECROSANE213545%AddosanESTEP20610%NaphthenicBaseO
14、il42%CONTRAMOF-G2.5%CONTRAMJ30D0.5%Anapprox.8%emulsionofapreparationofBECROSANE2135,performanceester(inparticularAddosanESTEP206)inbaseoil(asabove)worksextraordinarywellforgeneralaluminiummachining.上述配方以上述配方以8%的稀释液用于铝加工具有非常突出的效果的稀释液用于铝加工具有非常突出的效果Appearance外观visual目测translucent半透明Emulsionstability乳化安
15、定性visualafter24hrs0mloil/0mlcreampHvalue,5%inwater5%水溶液的PH值DIN513699.1CorrosionprotectionDIN51360part2Note0at4%vol防锈13TheLubrizolCorporation2007,allrightsreservedSemiSyntheticAluminum铝加工半合成液润滑效果45%BECROSANE2135+环烷基油VS10%ADDOSANESTEP206+45%BECROSANE2135+环烷基油14TheLubrizolCorporation2007,allrightsreser
16、vedHighoil-Semi-SyntheticPackages与高含油半合成复合剂的复配配方Baseoil基础油基础油41.7045.7050.70BECROSANE2137H/LUBRIZOL568342.00-BECROSANE2135-40.00-BECROSANE2152-35.00ADDOSANESTEP20610.010.010.0CONTRAMMBOorST-12.002.002.00CONTRAMJ30D0.300.300.30Quicklin131.00-Water水水3.00-TD25/30-2.002.00LUBRIZOL5674消泡剂消泡剂0.10-0.1015Th
17、eLubrizolCorporation2007,allrightsreservedPerformance性能E2137H/LUBRIZOL5683E2135E2152Appearance外观外观yelow-lightbrown,clear黄色淡棕色，透明Yelowlightbrown,clear黄色淡棕色，透明Yellowlightbrown,clear黄色淡棕色，透明Appearanceemulsion(5%in20dH)乳液外观乳液外观Fresh新鲜乳液Translucent半透明Translucent半透明Translucent半透明after24h24小时后translucent-n
18、ocream半透明无浮皂translucent-nocream半透明无浮皂translucent-nocream半透明无浮皂corrosion-DIN51360-part2防锈防锈2%-class0-12%-class1-22%-class2corrosion-IP287防锈防锈breakpoint2%breakpoint3%breakpoint3%pH-value-(5%in20dH)pH值值9.209.409.40foamcharacteristic泡沫5%in10dHnofoam无泡沫nofoam无泡沫nofoam无泡沫5%in5dH70ml-10ml-0ml50ml-0ml-0ml70
19、ml-10ml-0mlReichertwithoutlubricity磨斑磨斑/未加润滑剂未加润滑剂30.0mm31.3mm33.2mmReichertwith磨斑磨斑/加入加入ADDOSANESTEP20623.0mm23.8mm24.3mm16TheLubrizolCorporation2007,allrightsreservedMetalworking-CorrosionInhibitors防锈剂17TheLubrizolCorporation2007,allrightsreservedBecrosan2131TechnologyTrivialname:Triazinetrisamino
20、hexanoicacid三嗪三氨基己酸三嗪三氨基己酸IUPAC:6,6,6-(1,3,5-triazine-2,4,6-triyltriimino)-trihexanoicacidCAS-No.80584-91-4MW:468.6g/mol18TheLubrizolCorporation2007,allrightsreservedBecrosan2131TechnologyApplications应用应用Neutralizedwithalkali/alkanolamineperformsasveryeffectivecorrosioninhibitor用碱用碱/醇胺中和后是非常有效的腐蚀抑制剂
21、醇胺中和后是非常有效的腐蚀抑制剂AppliedinalltypesofwaterbasedsystemsMetalworkingfluids(Semi-syntheticandsyntheticfluids)可以用于所有类型的水基体系金属加工液可以用于所有类型的水基体系金属加工液(半合成和合成液半合成和合成液)Highwaterbasedhydraulicfluids(HFC)可用于高水基液压液可用于高水基液压液(HFC)Engineandothercoolingsystems用于发动机和其他冷却体系用于发动机和其他冷却体系19TheLubrizolCorporation2007,allrig
22、htsreservedBecrosan2131TechnologyBenefits优点优点Veryeffectivecorrosioninhibition高效防锈高效防锈Doesnotformresinousfilmsorgumsonmetals不会在金属表面形成树脂或胶状膜不会在金属表面形成树脂或胶状膜Lowfoaming低泡沫低泡沫Noaluminumstaining(dependingonamineused)不会造成铝腐蚀不会造成铝腐蚀Compatiblewithhardwaterupto2000ppm耐硬水能力高达耐硬水能力高达2000ppmCanbeusedforcorrosioni
23、nhibitionofmulti-metalsystems,mightbeimprovedbyadditionofSkosanorKSP24/531andheptanoic/ison.Acid可以用于含多种金属的体系，添加可以用于含多种金属的体系，添加SkosanorKSP24/531可提高防腐蚀效果可提高防腐蚀效果PROVEN:Notendencytoformnitrosamines(5fruleinUS)不会生成亚硝胺不会生成亚硝胺Excellentairrelease良好的空气释放性能良好的空气释放性能20TheLubrizolCorporation2007,allrightsreser
24、vedBecrosan2128TechnologyTrivialname:Tolylsulfonamidohexanoicacid对甲苯磺酰氨基己酸对甲苯磺酰氨基己酸IUPAC:4-MethylphenylsulfonylaminohexanoicacidCAS-No.78521-39-8MW:285.0g/mol21TheLubrizolCorporation2007,allrightsreservedBecrosan2128TechnologyApplications应用应用:Neutralizedwithalkali/alkanolamineperformsasveryeffective
25、corrosioninhibitor用碱用碱/醇胺中和后是非常有效的腐蚀抑制剂醇胺中和后是非常有效的腐蚀抑制剂AppliedinalltypesofwaterbasedsystemsMetalworkingfluids(Semi-syntheticandsynthetic)可以用于所有类型的水基体系金属加工液可以用于所有类型的水基体系金属加工液(半合成和合成液半合成和合成液)Watertreatmentprocesses水处理过程水处理过程Presswaters水压系统水压系统Industrialcleaners工业清洗剂工业清洗剂Off-shorelubricants海上石油海上石油/天然气
26、钻探用润滑剂天然气钻探用润滑剂Waterbasedhydraulicfluids水基液压液水基液压液Water/glycolcoolingsystems(+KSP24/531)水水/乙二醇冷却体系（可加入乙二醇冷却体系（可加入KSP24/531提高抗腐蚀效果）提高抗腐蚀效果）22TheLubrizolCorporation2007,allrightsreservedBecrosan2128TechnologyBENEFITSVeryeffectivecorrosioninhibitionforferrousmetals,castiron,ferrousalloysatapHvalueof8.p
27、H值值8时，对铁、铸铁和铁合金的防锈非常有效时，对铁、铸铁和铁合金的防锈非常有效Easyhandling,easysoluble,nondusting,odorless容易使用，容易溶解容易使用，容易溶解,不会产生粉尘，不会产生粉尘，无味无味Nostickyresiduesafterwaterphaseevaporation水相挥发后无粘性残留物水相挥发后无粘性残留物Lowfoaming低泡低泡Compatiblewithhardwaterupto2000ppm耐硬水能力耐硬水能力2000ppmNostainingonaluminum(dependingonamineused)不会造成铝变色不
28、会造成铝变色Notendencytoformnitrosamines不会生成亚硝胺不会生成亚硝胺Higherthermalstabilitythanmetalsoaps比金属皂具有更好的热稳定性比金属皂具有更好的热稳定性23TheLubrizolCorporation2007,allrightsreservedFullysyntheticbasedonBECROSAN2131全合成液的建议配方20%Triethanolamine三乙醇胺5%Monoethanolamine单乙醇胺16%BECROSAN21312,5%Isononanoicacid异壬酸0,5%SkosanorKSP5310,5
29、%CONTRAMNFK55,5%Water水DIN51360T2(Chipfiltertest)防锈（滤纸铁屑法）=2,5%class0pH-value(3%inDI-water)pH值（在3%去离子水中） =9,2Foambehaviour(5%in10dH-water)泡沫 =70ml30ml0mlReichert(5%inDI-water,100m,1,5kg)磨斑 =30,6mm/GM10024TheLubrizolCorporation2007,allrightsreservedStartingFormulationGrinding/Machiningmoreseveremachin
30、ing用于更高负荷的磨削/切削配方Component成分%ByWeight重量%Triethanolamine三乙醇胺20Monoethanolamine单乙醇胺5BECROSAN213110Water水balanceADDCO410P5ADDCOMLB10X10SKOSANORKSP5310,5Bactericide/fungicide杀菌剂2-325TheLubrizolCorporation2007,allrightsreservedSemisyntheticbasedonBECROSAN2131半合成配方32,0%Baseoil基础油8,0%ADDCONATEM15,5%Trietha
31、nolamine三乙醇胺2,0%Monoethanolamine单乙醇胺7,5%BECROSAN21282,0%BECROSAN21312,5%TD25/307,5%Couplingagents(fattyalcohol)偶合剂15,0%Water水5,0%BECROSANC656(fattyacidamide脂肪酸酰胺)2,5%CONTRAMST-10,5%CONTRAMJ30DAppearance外观Clear,yellow黄色透明Emulsion乳液Translucent半透明DIN51360T2(Chipfiltertest)防锈 =2,5%class0pH-value(3%inDI-
32、water) pH=9,326TheLubrizolCorporation2007,allrightsreservedUseOfAlkanolamidesInMetalworking金属加工液中链烷醇酰胺的应用Emulsifier做乳化剂Functionsasaprimaryorsecondaryemulsifierino/wmetalworkingformulations在水包油型乳化油配方中可做主乳化剂或助乳化剂使用LubricityAdditive润滑剂Amidesbasedonlongerchainedfattyacidsenhancelubricationpropertiestoaf
33、luid基于长链脂肪酸的酰胺有助于提高体系的润滑效果CorrosionInhibitor防锈剂Fattyacidalkanolamidesprovideextracorrosionprotectionforferrousmetals脂肪酸的链烷醇酰胺对黑色金属有良好的防锈效果.27TheLubrizolCorporation2007,allrightsreservedFattyamides/esters脂肪酸酰胺/酯STRENGTH优点优点Cheapcorrosioninhibitors是一种较便宜的防锈剂是一种较便宜的防锈剂Posttreatmentapplicationpossible可现
34、场添加可现场添加Lowclassificationlevel。Lowtoxicityprofile低毒性低毒性Someareliquid,easytohandle有一些产品是液体的，易操作有一些产品是液体的，易操作Usedforsemi-syntheticandsolubleoiltypefluids可用于乳化油和半合成液可用于乳化油和半合成液28TheLubrizolCorporation2007,allrightsreservedFattyamides/esters脂肪酰胺/酯Product产品产品Alk.amine胺的种类胺的种类Appea-rance外观外观Viscosity40C黏黏
35、度度TAN酸值酸值TBN碱值碱值Solubility溶解性溶解性CP-51360/2SOE+2%am.5%inw.(orig:cl.3,0,9,2)防锈（浓缩液中加防锈（浓缩液中加2%，5%稀释）稀释）B.210EMEAPasty膏状-810Emuls.可乳化cl.2,pH9.2B.210MMEAPasty膏状-153Emuls.可乳化cl.2,pH9.1B.210RDEALiquid液体3855130Emuls.可乳化cl.1,pH9.1B.210DIIDEALiquid液体1701435Emuls.可乳化cl.1-2,pH9.0B.541MIPLALiquid/pasty液态/膏状1503
36、9Emuls.可乳化cl.2,pH9.0B.C656DGALiquid液体2005010Soluble可溶cl.1-2,pH9.2B.228DEALiquid液体39015150Dispers.水分散cl.0-1,pH9.2B.583TEA/MEALiquid液体2105052Emuls可乳化cl.0-1,pH9.1B.2021DETAWaxy蜡状4560C3.524Insol.不溶cl.2,pH9.229TheLubrizolCorporation2007,allrightsreservedPerformance性能18%LUBRIZOL5475in100Nbaseoil18%LUBRIZO
37、L5475+2%BECROSAN583in100Nbaseoil18%LUBRIZOL5475+4%BECROSAN583in100NbaseoilAppearance外观外观yelow-lightbrown,clear黄色淡棕色，透明Yelowlightbrown,clear黄色淡棕色，透明Yellowlightbrown,clear黄色淡棕色，透明Appearanceemulsion(5%in20dH)乳液外观乳液外观0mloil/0.3mlcream0mloil/0.1mlcream0mloil/0.1mlcreamcorrosion-DIN51360-part2防锈防锈5%-class
38、25%-class15%-class0corrosion-IP287防锈防锈breakpoint5,5%breakpoint4,5%breakpoint4%pH-value-(5%in20dH)9.209.409.40foamcharacteristic泡沫泡沫5%in10dHnofoam无泡沫nofoam无泡沫nofoam无泡沫5%in5dH70ml-10ml-0ml100ml-40ml-0ml100ml-50ml-0mlReichert磨斑磨斑34.0mm31.3mm28.2mm30TheLubrizolCorporation2007,allrightsreservedADDCONATES
39、tartingFormulationSemiSynthetic建议起始配方建议起始配方半合成半合成Baseoil基础油基础油30.00ADDCONATEM10.00DEG2.00TEA10.00TD25/301.00GuerbitolC162.50BECROSAN(TM)C6567.50Isononanoic异壬酸异壬酸1.00EmulsogenM0.50Water水水35.50Appearance外观Clearyellowliquid黄色透明液体Appearance-emulsion乳液外观Translucent半透明pH-value(3%in20dH)PH值9.15Corrosion(DI
40、N51360-2-4%)防锈Class0-131TheLubrizolCorporation2007,allrightsreservedADDCONATEStartingFormulationSemiSynthetic建议起始配方建议起始配方半合成半合成baseoil基础油基础油32.00ADDCONATEM8.00BECROSANC2141(carboxylicacidsalt羧酸盐羧酸盐)25.00TD25/302.50EmulsogenM5.003370V2.50Water水水15.00MEA2.00BECROSANC656(Fattyacidamide)5.00CONTRAMST-12
41、.50CONTRAMJ30D0.50Appearance外观Clearyellowliquid黄色透明液体Appearance-emulsion乳液外观Translucent半透明pH-value(3%in20dH)PH值9.3Corrosion(DIN51360-2-4%)防锈Class032TheLubrizolCorporation2007,allrightsreservedBiocides杀菌剂杀菌剂33TheLubrizolCorporation2007,allrightsreservedBiocidereview:34TheLubrizolCorporation2007,allri
42、ghtsreservedBiocidereview:Micro-organismslike微生物喜欢Awetenvironment潮湿环境Temperature温度Dust尘土Andcertainelementsasfoodstuff以及某些可以作为食物的元素WhicharegiveninallMETALWORLKINGFLUIDS这些在金属加工液中均可以得到满足这些在金属加工液中均可以得到满足35TheLubrizolCorporation2007,allrightsreservedBiocidereview:36TheLubrizolCorporation2007,allrightsres
43、ervedBactericides杀细菌剂杀细菌剂37TheLubrizolCorporation2007,allrightsreservedCONTRAMST-1N,N-methylenebismorpholineN,N-亚甲基双吗啉CAS#5625-90-138TheLubrizolCorporation2007,allrightsreservedCONTRAMMBOOxazolidine,3,3-methylenebis5-methyloxazolidine噁唑烷，3,3-亚甲基双5-甲基唑烷CAS#66204-44-239TheLubrizolCorporation2007,allri
44、ghtsreservedProductFeatures产品特性CONTRAMST-1ExceptionalstabilityinMWFconcentrates在浓缩物中特别稳定Doesnotdisruptbalanceofemulsionsystem不会干扰乳液体系的平衡Long-lastingefficacy(half-lifeis5-8months)长效（半衰期5-8个月）Uniquebalanceofoilandwatersolubilityimportantfeatureforemulsionsystems突出的水溶性和油溶性对乳液体系非常重要Lowtotalformaldehydec
45、ontent总甲醛含量低Evidenceforefficacyvs.mycobacteria对细菌特别有效Noskinirritation(noR43)对皮肤刺激性小（不用“贴标签”R43）Easycompatiblewithcommonusedfungicides(NaPyrion,IPBCs,BBits)容易与抗真菌剂并用WorksquitewellinpHranges7-11在pH7-11范围内特别有效Concentratetreatment:2,53,0%浓缩物加剂量2.5-3.0%Tanksidetreatment:notpreferred不推荐用于现场添加Stabilityprob
46、lemsofCONTRAMST-1assold:solidificationatcoldtemperaturesCONTRAMST-2,CONTRAMST1-50ST-1气温较低时，会凝固，可以使用CONTRAMST-2，ST-1/5040TheLubrizolCorporation2007,allrightsreservedProductFeaturesCONTRAMMBOBalancedperformancefortanksideorconcentratetreatment可以用于浓缩物或现场维护Greateroilsolubilitythancompetitivematerials油溶性
47、更好TanksidecomplementtoproductsprotectedbyST-1inconcentrate(avoidmicrobeacclimationandresistance)可以用作含有ST-1浓缩物产品使用时的现场维护（避免产生耐药性）Hightotalformaldehydecontentforfastactivityonexistingmicrobialgrowth高甲醛含量可以快速杀死细菌Basedonprimaryamine基于一级胺Concentratetreatment:2,53,0%浓缩物2.5-3.0%Tanksidetreatment:0,10,2%现场0
48、.1-0.2%HarderincorporationinMWFconcentratesadditionalcouplingagentsnecessary(fattyacids,ethoxylatedorfattyalcohols)需要一些偶合剂以帮助提高浓缩物的稳定性（脂肪酸，乙氧基化物或脂肪醇）41TheLubrizolCorporation2007,allrightsreservedProductFeaturesCONTRAM121Uniquebalanceofperformanceproperties优异的杀菌性能Quickactivityfortanksidecontrolcouple
49、dwithgoodstabilityinfluidconcentrates在浓缩物中优异的稳定性，同时可以用于现场添加ComplementtoCONTRAMST-1protectedfluidsalternatetanksidechemistrytoavoidmicrobeacclimationandresistancetooneparticularbactericidechemicaltype可以用作含有ST-1浓缩物产品使用时的现场维护替代品，避免某些特定种类的细菌产生抗药性Greateroilsolubilitythancompetitivetriazinesforimprovedcom
50、patibilityandstabilityinmetalworkingfluidemulsions比三嗪类杀菌剂的油溶性更好，和金属加工乳液有更好的兼容性和稳定性MorestablethanHHT比HHT更加稳定Concentratetreatment:2,53,0%浓缩物：2.5-3.0%Tanksidetreatment:0,10,2%现场：0.1-0.2%HarderincorporationinMWFconcentratesadditionalcouplingagentsnecessary(fattyacids,ethoxylatedorfattyalcohols)需要一些偶合剂以帮
51、助提高浓缩物的稳定性（脂肪酸，乙氧基化物或脂肪醇）42TheLubrizolCorporation2007,allrightsreservedProductFeaturesCONTRAMOF-GFast-actingperformanceagainstbacteriafortanksideapplication快速杀灭细菌，可用于现场添加ComplementtoCONTRAMST-1protectedfluidsalternatetanksidechemistrytoavoidmicrobeacclimationandresistancetooneparticularbactericidech
52、emicaltype可以用作含有ST-1浓缩物产品使用时的现场维护替代品，避免某些特定种类的细菌产生抗药性Amine-freeoptionforapplicationswherethisisofconcerntoformulatorsandendusers(Concentrateandtanksidetreatment)不含胺，可以用于一些特殊要求的配方或最终客户（浓缩物和现场添加）Near-neutralpHvaluetoavoiddramaticshiftinfluidpropertieswhenaddedtanksideandtominimizeimpactonbalanceofflui
53、dconcentrates中性pH值，对浓缩物或现场添加时对pH值得冲击小ParticularefficiencyagainstMycobacteria主要针对细菌Concentratetreatment:2,53,0%浓缩物：2.5-3.0%Tanksidetreatment:0,10,2%现场添加：0.1-0.2%HarderincorporationinMWFconcentratesadditionalcouplingagentsnecessary(fattyacids,ethoxylatedorfattyalcohols)需要一些偶合剂以帮助提高浓缩物的稳定性（脂肪酸，乙氧基化物或脂肪
54、醇）43TheLubrizolCorporation2007,allrightsreservedProductFeaturesCONTRAMNBF-34Formaldehydefree,basedonIsothiazolinon不含甲醛，基于异噻唑啉基Fast-actingperformanceagainstbacteriafortanksideapplication快速起效，用于现场添加Concentratetreatment:notpreferred%不推荐用于浓缩物Tanksidetreatment:0,10,175%现场添加：0.1-0.175%EU:Atanapplicationle
55、velofmax.0.175%inthefinishedfluidtherequirementsofthe28thATPdirectivearefulfilled.ThelevelofCMI/MIisbelow15ppm.44TheLubrizolCorporation2007,allrightsreservedKeyPhysicalProperties:TotalFormaldehydeContent总甲醛含量Product%CH2OassuppliedCONTRAM101,HHT28-32CONTRAMST-115-16CONTRAMMBO43-45CONTRAM12123-27CONTR
56、AMOF-G42-4645TheLubrizolCorporation2007,allrightsreservedPerformanceProfilePRODUCTCONTRAMST-1CONTRAMMBOCONTRAMOF-GCONTRAM121Hexahydrotriazene(HHT)ConcentrateStability浓缩物安定性+TankSideEfficacy现场维护效率+Long-TermStability储存安定性+-+-OilSolubility油溶性+-SkinSensitisationLabeling(EU)皮肤刺激性标签(EU)NONONOR431.0%concen
57、trationR430.1%concentration46TheLubrizolCorporation2007,allrightsreservedEfficacyinMIC-(minimalinhibitionconcentrationinppm)onBacteria:MICMinimumInhibitionConcentrationoftheproductsinppmonfollowingmicroorganismMIC针对下列细菌的最小抑菌浓度（针对下列细菌的最小抑菌浓度（ppm)Muster/bacteriaStaph.aureus金黄色葡萄金黄色葡萄球菌球菌Ps.aerug绿脓杆绿脓杆
58、菌菌E.Coli大肠杆大肠杆菌菌Ps.putida恶臭假恶臭假单胞菌单胞菌Ps.fluores.Klebs.Oxytocca克雷伯克雷伯氏杆菌氏杆菌属属Legion.longb.Myco-bact.avCONTRAMST-11000100010005005001000250CONTRAMMBO25025025025025025050100CONTRAM121500500500500500500250500CONTRAMOF-G25025025025025025050CONTRAMNBF212501001001001001005047TheLubrizolCorporation2007,allr
59、ightsreservedMICMinimuminhibitionconcentrationinppmonfollowingmicroorganisms:MusterAcremoniumspec.枝顶包属Candidaspec.念珠菌属Fusariumspec.镰刀菌属CONTRAMST-1200020002000CONTRAMMBO5001000500CONTRAM121100010001500CONTRAMOF-G5001000500CONTRAMNBF21500100100EfficacyinMIC-(minimalinhibitionconcentrationinppm)on:Fung
60、ie48TheLubrizolCorporation2007,allrightsreservedFungicides杀真菌剂杀真菌剂SelectionConsiderationsCONTRAMNFKfungicideandCONTRAM J( IPBCs)fungicide49TheLubrizolCorporation2007,allrightsreservedCharacteristicsofCONTRAMNFKfungicideStabilizedsolutionofsodiumpyrithioneinwater吡啶硫酮钠的水溶液Watersoluble溶于水Veryeffectivef
61、ungicide(yeastandmold)高效杀真菌剂（酵母菌和霉菌）Notconsideredfastactingduetomodeofaction非快速杀灭Sometimesantibacterial有时对细菌有效Non-irritatingandnon-sensitizingtohumans对人的皮肤没有影响Hasbeenshowntohavenopotentialforskinsensitization,evenat760timesthenormalenduselevel即使浓度高于推荐的760倍，也没有发现皮肤过敏50TheLubrizolCorporation2007,allri
62、ghtsreservedCharacteristicsofCONTRAMNFKfungicideIroncanbeintroducedintometalworkingfluidconcentratesthroughrawmaterials通过原料可能带入铁离子Resultingingrayorblackformulations导致工作液颜色变灰或发黑Water-insolubleironpyrithionemayprecipitate非水溶性的吡啶硫酮铁可以析出Canbereversedwithadditionsofironspecificsequesteringagents可以通过添加铁离子
63、螯合剂来还原工作液的外观EDTA(Naformbest)最好使用EDTA钠盐-NFKfungicideisstabilizedinthisform,thereforecanberecommendedforuseincastirongrindingoperations可以推荐可以推荐NFK用于铸铁磨削加工用于铸铁磨削加工51TheLubrizolCorporation2007,allrightsreservedCharacteristicsCONTRAMNFKpHProductpHisalkalinetypically9-11产品的pH范围9-11WorkswellinpHrangeofmost
64、formulations在广泛pH范围内有效Goodthermalstability热稳定性好Thermaldecomposition(powder)250C热分解温度（粉末）250CGoodstabilityinformulationswhichmightbeshippedorstoredinwarmclimates在配方中的稳定性好，可以储存在温暖的气候条件52TheLubrizolCorporation2007,allrightsreservedCharacteristicsofIPBCindustrialfungicideHereonoutreferredtoasIPBCIodopro
65、pynylbutylcarbamate碘代丙炔基丁基氨基甲酸酯99%powderandvariousglycolsolutionblends99%活性含量的粉末和各种浓度的溶液Moreoilthanwatersoluble油溶性Contains1atomofiodinepermoleculeofIPBC每分子的IPBC含有1个碘原子Veryeffective,relativelyfastactingfungicide高效，相对快速杀灭真菌53TheLubrizolCorporation2007,allrightsreservedCharacteristicspHNoinherentpHPref
66、ersneutralpHformulations更倾向用于中性pH配方ChemicalinstabilitywhenpH9.0pH9.0可能会导致不稳定Moderatethermalstability(powder)粉末IPBC的热稳定性中等Temperatureofdecomposition150C热分解温度150CMeltingpoint65C熔点65CNotwellsuitedforstorageinformulationswhichmightbeshippedorstoredinwarmclimates不太适合用于海运到或储存于热带地区的产品中Caremustbetakenwhenma
67、kingMWFconcentrateswhichrequireheat对需要加热调配MWF浓缩物时，必须当心SolubleOilandSemi-syntheticblends可溶油和半合成液Whenpossibleallowblendtocool45C冷却到9.0)在高pH(9.0)体系化学降解Rapidchemicaldegradationatbothtemperatures两种温度条件都会导致快速化学降解RelationshipbetweenpHandstabilitymostapparent稳定性和pH的关系很明显lifeatambienttemp3-6weeks(exceptforTE
68、A)半衰期3-6周（除TEA以外）lifeatelevatedtemp1-2weeks(40C)半衰期1-2周（40C）StrongrelationshipnotedbetweensolutionpHandstability稳定性和pH的关系紧密BetterstabilityinlowerpHformulations低pH配方的稳定性好Primaryaminesmostaggressive一级胺影响大KOH-Rapiddegradationnotedathighestlevel(pH) KOH-在加剂量高时导致快速降解63TheLubrizolCorporation2007,allrights
69、reservedThankYou(Xiexie)Questions?64TheLubrizolCorporation2006,allrightsreservedRustpreventivesforMetalworkingFluidsAlternativestoALOX2028S防锈剂ALOX2028S的替代品TheLubrizolCorporation2007,allrightsreservedALOX2028S:manufacturingconstraintshavelimitedourabilitytosupplyproductforcontinualgrowth.Alternativep
70、roductshavebeendevelopedthatprovidesimilarorbetterperformancetomeetgrowthneeds.目前ALOX2028S的生产能力已近饱和，但新的产品可以作为ALOX2028S的替代品使用。CalciumBased含钙ALOX2100(AdvancedProtection提供更强的防锈能力)BariumBased含钡ALOX2028F(AlternativeRM/process)66TheLubrizolCorporation2006,allrightsreservedALOX2100MetalProtectionforMetalwo
71、rkingFluids用于金属加工液的防锈保护AdvancedProtectionFromThin-FilmTechnology性能先进的薄膜防锈技术TheLubrizolCorporation2007,allrightsreservedAdvancedProtection优异的防锈保护能力优异的防锈保护能力ALOX2100Isathin,waxyfilmrustpreventivecompoundofferingexceptionalsaltsprayprotectiontoprotectivefluids形成薄的，蜡状防锈膜，提供优异的盐雾防护性能Iscapableofexceeding1
72、00hoursofprotectioninsaltsprayenvironmentsasmeasuredbytestmethodASTMB-117按照ASTMB-117方法测定，可以提供大于100小时的盐雾防护68TheLubrizolCorporation2007,allrightsreservedHowdoesitwork?防锈机理防锈机理ALOX2100worksbydisplacingwaterfromthemetalsubstrateandcreatingaprotectivebarrierbetweenthemetalandtheatmosphere.ALOX2100通过置换金属表
73、面的水分，在金属和大气之间形成防护膜达到防锈效果ALOX2100providesimprovedattractiontometal,boostingitscorrosionprotectionandwaterdisplacingproperties.ALOX2100能够对金属提供更强的吸附能力，促进防锈效果和水置换性能69TheLubrizolCorporation2007,allrightsreservedAdvancedBenefits优点优点Exceptionalsaltsprayprotectionfromathin-filmcompound:具有优异盐雾防护性能的薄膜防锈剂Excel
74、lenthumiditycabinetprotection:优异的潮湿箱防护性能：Greaterthan60daysprotection60天以上的防护效果天以上的防护效果Outstandingwater-displacingproperties:突出的水置换性Norust无锈无锈PerformanceHighlights突出的优点突出的优点ALOX2100iscapableofexceeding100hoursprotectioninsaltsprayenvironmentsasmeasuredbyASTMB-117testmethod超过100小时的盐雾防护能力Submersepaneli
75、ndistilledwaterfor5secondsSubmersepanelinRPsolutionfor15secondsNeatandWatercontaminatedStatichumiditychamber77F(25C)for1hour70TheLubrizolCorporation2007,allrightsreservedAdvancedBenefits优异性能优异性能Water-separating.Inuserustpreventivemustshedwatercontaminationrapidlyandcompletely水分离性。防锈油必须具备将混入的水分完全、彻底分
76、离出去Testtomeasuretheabilityofarustpreventivetoseparatewatercarryoverfromrinseoperations用来测定防锈油浸渍涂油时将混入的水分分离的能力75mLofRPsolution75ml防锈油25mLwater25ml水Invertsixtimesina100mLgraduatedcylinderRecordtimetoseparate25mLofwaterModificationsarepossibletobettersimulatespecificrealworldconditions可以调整检验方法以模拟现场工况4m
77、LCuff20%ALOX2100inD-80SolventWaterSeparationbefore6Inversions6次翻转1:00AfterInversions1:45AfterInversionsCompleteSeparationin2:302分30秒彻底分离71TheLubrizolCorporation2007,allrightsreservedAdvancedBenefitsNon-stainingsafeforuseoncoiledorstackedmetalswhendilutedinmoststandardaliphaticsolvents无锈斑用脂肪族溶剂稀释后可以安
78、全地用于钢卷或叠放的金属防锈CoatpanelswithRPsolution用防锈油涂片Neat纯油Contaminatedwithwater或添加一些水到防锈油中Stackpanelsinasandwicharrangement叠放Store180F(82.2C)for24hours82.2C存放24小时Nostainorrust无锈斑或锈蚀无锈斑或锈蚀Freeofbariumandotherheavymetals不含钡和其他重金属72TheLubrizolCorporation2007,allrightsreservedApplicationFlexibility多样化的应用多样化的应用A
79、LOX2100isalsodesigned:ALOX2100在设计时还考虑到用于：Toprovideexcellentsolubilityinverylowaromaticcontentsolvents,whichaddressesenvironmentalandsafetyconcerns在低芳烃溶剂中有优异的溶解能力，对环境和安全有益Primarilyforuseinpetroleumsolventbutcanalsobeusedinoildilutionsorcombinationsofboth,offeringexcellentsolubility.主要用于石油溶剂中调配稀释液，但也和
80、矿物油或矿物油、溶剂油并用73TheLubrizolCorporation2007,allrightsreservedALOX2100vsTheCurrentGenerationProductDiluent%Temp温度,oCResult结果AX2100MineralSpirits*溶剂油NaphthenicOil*环烷基油ParaffinicOil*石蜡基油201010000SlightHaze轻微混浊Clear透明Hazy混浊StandardProductCMineralSpirits溶剂油NaphthenicOil环烷基油ParaffinicOil石蜡基油20101000RTSlight
81、Haze轻微混浊HazyGel轻微胶状Hazy混浊StandardProductBMineralSpiritsNaphthenicOilParaffinicOil20101050RTSlightHaze轻微混浊Clear透明Hazy混浊*ExxsolD-40,alsosolubleinD-60,D-80&IsoparM(w/similarsolubilitytestresults)*100SUS,alsosolublein60SUS&200SUS(solubilityimprovesw/60SUS)100SUS环烷基油，也可以60SUS和200SUS（使用60SUS可以提高溶解性）*Group
82、I,II&III74TheLubrizolCorporation2007,allrightsreservedALOX2100Performance性能性能AX2100wt%MineralOil1矿物油矿物油wt%AliphaticPetroleumSolvent2脂肪族溶剂脂肪族溶剂wt%HumidityCabinet3Days/Failure潮湿箱潮湿箱天天/失败失败5%SaltSpray4Hours/Failure5%盐水喷雾试验盐水喷雾试验小时小时/失败失败15.085.060+64961681841ISO46naphthenicoilusedfortestingISO46环烷基基础油2
83、Petroleumsolventswithverylowaromaticcontentcanbeused也可以使用低芳烃的石油溶剂3ASTMD-1748,polishedcoldrolledsteelpanels打磨抛光冷轧钢片4ASTMB-117,sandblastedcoldrolledsteelpanels喷砂冷轧钢片75TheLubrizolCorporation2007,allrightsreservedApplications应用应用ALOX2100canbeformulatedtoproducemanytypicalprotectivefluids/oilsincluding:A
84、LOX2100可以用来调配诸多典型的防锈油，包括：可以用来调配诸多典型的防锈油，包括：SlushingOils（脱水）防锈油ProtectiveStorageFluids（储存防护）防锈油ProtectiveShippingFluids（运输过程防护）防锈油DipTankFluids浸渍防锈油ALOX2100isparticularlyeffectiveinprotectingmetalshippingoverseasandformetalwarehousedneartheoceanALOX2100特别适用于海运或近海仓储的金属防护Unlikealternativeproductsdesign
85、edforimprovedsaltsprayprotection,whichrelyonthickhard-to-removefilms,ALOX2100iseasilyremoved和其他依靠厚的硬膜来提高盐雾防护性能的防锈剂不同，ALOX2100易于去除76TheLubrizolCorporation2007,allrightsreservedPerformanceonnickelcoatedparts在镀镍工件的防护性能在镀镍工件的防护性能ThinWaxyFilm:薄的蜡状膜ALOX210015%100SUSparaffinicoil100SUS环烷基油5%AliphaticPetrol
86、eumSolvent脂肪族溶剂80%5%SaltSpray,ASTMB117,90Hours5%盐雾试验，ASTMB117，90小时77TheLubrizolCorporation2007,allrightsreservedSuggestedFormulations建议配方建议配方ForMaximumSaltSprayProtection要获得最好的盐雾防护ALOX210020%AliphaticPetroleumSolvent80%脂肪族石油溶剂ForGeneralPurposeRustPreventative普通用途的防锈保护ALOX21005-15%AliphaticPetroleumS
87、olventBalance脂肪族石油溶剂ForThin,OilyFilmRustPreventative/LubricantCompound薄的，油膜防锈油/润滑多功能油ALOX210010-15%MineralOil10-15%矿物油AliphaticPetroleumSolventBalance脂肪族石油溶剂78TheLubrizolCorporation2007,allrightsreserved5%SaltSpray,ASTMB117,90Hours79TheLubrizolCorporation2006,allrightsreservedALOX2028FMetalProtectio
88、nforMetalworkingFluids用于金属加工液的防锈保护TheLubrizolCorporation2007,allrightsreservedALOX2028SvsALOX2028FSolubilityTest溶解性溶解性AX2028SAX2028FExxsolD-40ClearClearExxsolD-60ClearClearExxsolD-80ClearClearExxsolD-95ClearClearIsoparMClearClearSUAFClearClearMotivaStar4Clear,ppt.ClearESSO150NClearClearESSOJurongCle
89、ar,ppt.Clear265-X7768HClear,ppt.ClearPhysicalPropertiesAX2028SAX2028FAcid#酸值5.08maxSpecificGravity比重0.970.89Color色度6.5max2.3%Barium钡含量4.62.6Viscosity,cSt40C黏度20781TheLubrizolCorporation2007,allrightsreservedALOX2028SvsALOX2028FWaterSeparation水分离水分离AX2028SAX2028F15%in140SolventTimetoSeparate分水时间3:421
90、:47WaterLayer水层Clear清澈Clear清澈OrganicLayer油层Clear请20C/55HHumidityCabinet潮湿箱潮湿箱AX2028SAX2028F5%in140SolventDays/Failure60+60+SaltSprayCabinet盐雾盐雾AX2028SAX2028F15%in140SolventHours/Fail(SB)2440(25%)WaterDisplacement水置换水置换AX2028SAX2028F5%in140Solvent1:1DilutionPassPassEmulsionPassPassStackStainTestAX202
91、8SAX2028F15%in140SolventPassPassWaterContaminationPassPassColdTempSolubility低温稳定性低温稳定性AX2028SAX2028F15%in140SolventAt5CHazyLiqHazyLiqAt-20CHazyLiqHazygelReturntoRTClearClear82TheLubrizolCorporation2006,allrightsreservedLUBRIZOL5636&LUBRIZOL5477NewSolublePackagesForChina最新的乳化油复合剂最新的乳化油复合剂TheLubrizolC
92、orporation2007,allrightsreservedCustomerswilluseLubrizol5636because客户选择Lubrizol5636是因为Lubrizol5636isPrimaryemulsifierforusewithnaphthenicbaseoils用于环烷基油的主乳化剂Componentemulsifierforusewithnaphthenicandparaffinicbaseoils可用于石蜡基和环烷基的乳化剂单剂Lowfoamemulsifier-mostimportantfeature低泡沫低泡沫-最重要的特征最重要的特征Effectiveat
93、lowtreat低加剂量Foruseinsolubleoilsandsemi-syntheticformulations用于可溶油和半合成液配方Supplementallubricityadditive对润滑性能有补充效果Lubrizol5636offersAbilitytoproducelowfoamemulsionproductsthatsolveproblemsatenduseroperations可调配低泡沫水基液，解决了最终客户的苦恼可调配低泡沫水基液，解决了最终客户的苦恼Reducedrelianceonanti-foamtreatmentsthatprovidetemporary
94、solutions减少了对消泡剂的依赖，因为消泡剂仅提供暂时的效果Ppetitorsusingtraditionalemulsionapproaches和竞争对手使用传统乳液技术的产品相比，产品性能更加优化84TheLubrizolCorporation2007,allrightsreservedLUBRIZOL5636:两种用法Asanemulsifier作乳化剂使用Alternativetomediummolecularweightsodiumsulfonate可作为中等分子量的磺酸钠的替代品使用Significantlymorepowerfulatemulsifyingoilintowa
95、terthansodiumsulfonate对调配水包油型的乳化液比磺酸钠更为有效Asapackage作为复合剂使用Traditionalsolubleoilformulationswithlowtreatrates可以较低的添加量配制乳化油配方Biocidecompatibility与杀菌剂相容性好EnhancedEP/Lubricityversions提高极压/润滑效果Highperformance,highoilsemi-synthetics可用于高性能高含油量的半合成液配方Aluminummachining用于铝加工Enhancedferrouscorrosionversions能提高
96、对铁系材质的腐蚀保护85TheLubrizolCorporation2007,allrightsreservedLUBRIZOL5636:TraditionalSolubleOil传统乳化油配方中的应用LUBRIZOL563613.5%NaphthenicOil环烷基油86.5%Stableemulsionswithlowtreatrate在较低添加量下即可形成稳定乳液Virtuallyzerofoamingtendency无泡沫倾向Supplementallubricitycontribution增强配方润滑性能Compatiblewithtypicalfluidenhancements与常
97、用的功能添加剂相容性良好86TheLubrizolCorporation2007,allrightsreservedLUBRIZOL563613.5%10%8%5%*Emulsifiertreatrateinnaphthenicoil100SUS环烷基油中乳化剂的添加量LUBRIZOL5636demonstratessignificantlystrongeremulsifyingpowerthansodiumsulfonate,aslowas5%treatrateinoilLUBRIZOL5636即使在低达5%的添加量时，也表现出比磺酸钠更为优异的乳化性能。87TheLubrizolCorpo
98、ration2007,allrightsreservedLUBRIZOL5636:FoamTendency泡沫倾向NoDefoamerUsed未使用消泡剂LowHardnessTapWater(30ppm)低硬度自来水(30ppm)ZeroFoam5SecondsAfterPumpShutOff泵关闭5秒后泡沫高度为088TheLubrizolCorporation2007,allrightsreserved酰胺硼酸酰胺磷系极压剂石蜡基油储存安定性LZ5636LZ5636调配高含油微乳液调配高含油微乳液89TheLubrizolCorporation2007,allrightsreserved
99、储存安定性循环考察乳液安定性90TheLubrizolCorporation2007,allrightsreserved防锈性5%inTapWater5%inTap400ppmWater3%inTap400ppmWater3%inTapWater91TheLubrizolCorporation2007,allrightsreservedLUBRIZOL5636:FeaturesSummary特点总结Emulsificationwithoutfoam乳化时几乎无泡沫Powerfulemulsifierforconsiderationaslowtreatcomponent做乳化单剂使用在低添加量下
100、，即可取得良好的乳化效果Forformulatorswhodesireproductcustomizationflexibility对于希望根据不同客户的要求来灵活设计配方的化学师来讲，这一点非常实用。Capableofperformingassolubleoilpackagewithverylowtreatrates在较低添加量下，即可作为乳化油复合剂来应用。Compatiblewithtypicalsolubleoilenhancements与各种常用于乳化油的功能助剂相容性良好。Abletoproducehigherperformancemicro-emulsionproductswit
101、hlowtreatrate可以较低添加量来生产高性能微乳液。Contributessupplementallubricity;lowaluminumstainingtendency能够增强配方的润滑性，对铝基本无腐蚀。92TheLubrizolCorporation2007,allrightsreservedLUBRIZOL5636:BenefitsSummary特点总结AbilitytoproducelowfoamemulsionproductsthatsolveproblemsatenduseroperationsLZ5636可配制低泡沫乳液，从而解决终端用户使用过程中出现的诸多问题。Re
102、ducerelianceondefoamertreatmentsthatprovidetemporarysolutions减少了对消泡剂的依赖性，消泡剂所能提供的只是短期和暂时的效果。Productperformancedifferentiationvscompetitorsusingtraditionalemulsionapproaches相比传统乳化技术，它可使产品性能差异化，满足各种不同需求NewchemistryfortheindustryalternativetosulfonatesthatofferlessperformanceanduncertainsupplyfutureLZ5
103、636是行业中新颖的化学品，可做为磺酸钠的替代品使用。磺酸钠与之相比性能较差，并且在将来供应很可能极不稳定。Economicallyviableapproachforawiderangeoffinishedfluidemulsiontypes&productperformancelevels对广泛的乳化液类型和不同性能和档次的产品，它都是一个经济可行的解决方案。93TheLubrizolCorporation2007,allrightsreservedLubrizol5477SOEPackageforParaffinicOilLubrizol5477-用于石蜡基油的全新可溶油复合剂Usedin
104、varietyofparaffinicbasestockwith3%ContramST-1可以和可以和3%ContramST-1并用于广泛的石蜡基油并用于广泛的石蜡基油Containscoppercorrosioninhibitor含有铜合金缓蚀剂Providesgoodhardwaterstability,highpHvalue,Cuprotection,goodbloomandrustprotection优异的硬水稳定性，较高的pH值，铜合金保护，自乳化性能和防锈保护UsedtomakeconventionalandEPtypesolubleoils可以调配通用和极压型乳化液Adjustm
105、entswithfattyacid,triethanolamineorothercouplingagentsmayberequiredtoobtainemulsionstabilitydesired可以使用脂肪酸、TEA或其他偶合剂来调整乳液安定性94TheLubrizolCorporation2007,allrightsreservedSOLUBLEBASE133U112CinESSO150SNBase133U112Cwt%15.0ESSO150SNwt%82.0ContramST-1wt%3.01.ConcentratestabilityIP311a)HighTemp50/14daysOK
106、b)LowTemp0/14daysOK2.pHvalue5%inDIH2O9.745%inShanghaitapwater(180ppm)9.463.EmulsionstabilityIP2635%in200ppm50Cream/Oil0.3/0.05%in400ppm50Cream/Oil0.3/0.14.RustProtectionIP287,5%100ppmrustarea1%200ppmrustarea1%5.CuCorrosion5%intapwater,ASTMD130100/3hrsClass1b5.FoamTestIP312,5%in180ppmstart120ml1min0(
107、3sec)6.Bloom自乳化性能自乳化性能Inversion1Formulateat15%inESSO150SN(orGaoQiao,DaLian)AdditionofContramST-1Excellenthardwaterstability95TheLubrizolCorporation2007,allrightsreservedSOLUBLEBASE133U112CinESSO150SNBase133U112Cwt%15.0ESSO150SNwt%82.0ContramST-1wt%3.01.ConcentratestabilityIP311a)HighTemp50/14daysOKb
108、)LowTemp0/14daysOK2.pHvalue5%inDIH2O9.745%inShanghaitapwater(180ppm)9.463.EmulsionstabilityIP2635%in200ppm50Cream/Oil0.3/0.05%in400ppm50Cream/Oil0.3/0.14.RustProtectionIP287,5%100ppmrustarea316316316D1743(Rust,distilledwater)passpassfail,trD1264(Washout,%)3.3%1.61.3D4049(Sprayoff,%)24.4%8.114.2Greas
109、ePerformanceofLubrizol86GRBasedGreaseLZ86GR磺酸钙润滑脂性能124TheLubrizolCorporation2006,allrightsreserved提高润滑脂高温流变性的添加剂Lubrizol5370CTheLubrizolCorporation2007,allrightsreserved提高润滑脂滴点LZ5370C硼酸脂类型，2.7%wt的硼提高锂基脂（12HSA）的滴点帮助复合锂基脂稳定滴点帮助提高极压和抗磨性加剂量1-3%与LZ1395复配可获得更高的滴点与其他竞争产品相比，与其他竞争产品相比，不通过欺瞒不通过欺瞒D2265滴点检测仪来获得
110、需要滴点检测仪来获得需要的滴点。实际上是改善润滑脂的高温流变性能来提高滴点。的滴点。实际上是改善润滑脂的高温流变性能来提高滴点。126TheLubrizolCorporation2007,allrightsreservedTestingASTMD2265:滴点测试仪GR640/GR-SP371-27-98ThermometerTestTubeTestCupTestGreaseAppliedtotheWallofCupThermometerDoesNotTouchGreaseAluminumBlockOven127TheLubrizolCorporation2007,allrightsreser
111、vedTestingASTMD2265:润滑脂滴点测试HeatingUnitwithObservationPorts“仪器欺瞒”是指将油完全从润滑脂中分离出去，形成一个长的油滴，悬挂在油杯上而不滴落-这样形成一个润滑脂具有很好高温滴点的假象。128TheLubrizolCorporation2007,allrightsreservedLithium12-HydroxystearateGreasesASTM D2265 Dropping Point Test ResultsMoDTP=Molybdenumdi(2-ethylhexyl)phosphorodithioate,anadditivet
112、ypicallyrecommendedat0.75%/wttoimprovethedroppingpointofgrease.123456BaseGrease10098.5979794.599.25LZ5370C1.53.01.51.5LZ13951.5LZ52354.0MoDTP0.75DropPoint(C)207263283316316205In simple lithium greases, MoDTP has NO effect129TheLubrizolCorporation2007,allrightsreservedLithiumComplexGreases(Azelaic Ac
113、id/12-HSA)ASTMD2265DroppingPointTestResults123456BaseGrease10098.5979794.599.25LZ5370C1.53.01.51.5LZ13951.5LZ52354.0MoDTP0.75DropPoint(C)316315313315316305MoDTP=Molybdenumdi(2-ethylhexyl)phosphorodithioate,anadditivetypicallyrecommendedat0.75%/wttoimprovethedroppingpointofgrease.In a good Li complex
114、, MoDTP has reduced the drop pt.130TheLubrizolCorporation2007,allrightsreservedFailedLithiumComplexGreases(Azelaic Acid/12-HSA)ASTMD2265DroppingPointTestResults123456BaseGrease10098.5979794.599.25LZ5370C1.53.01.51.5LZ13951.5LZ52354.0MoDTP0.75DropPoint(C)223282298316316283MoDTP=Molybdenumdi(2-ethylhexyl)phosphorodithioate,anadditivetypicallyrecommendedat0.75%/wttoimprovethedroppingpointofgrease.131TheLubrizolCorporation2007,allrightsreservedLZ5370C总结提高锂基脂（12HSA）的热抵抗能力滴点提高与加入量成比例.不影响其他功能剂的性能.可以帮助低滴点复合锂基脂，以获得正常的热抵抗能力.与锌盐（LZ1395/LZ5235）配合可获得更好的性能.132
