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1、 = y S K 2=3.03 8 10 2 )/(Lmol 7 HAco, = HClo, + NaAco, - NaClo, =390.7 121 eqcm HAco, =9.02 121 eqcm 0 /=0.023=1.69 K _ 2 )1/(V 5 10 8IR=iS KS l = K il ,K= 1000 c ,IR= 1000il c =V79 . 0 5 . 0126 1010105 33 9log=- 0.5115|ZZI25 C 1 ,/,/uvsmvs ,Cl 73.49mol50.14mol76.31mol (NaCl73.49mol50.14mol76.31mol
2、 (NaCl ,Cl 73.49mol50.14mol76.31mol (NaCl73.49mol50.14mol76.31mol (NaCl73.49mol50.14mol76.31mol (NaCl73.49mol50.14mol76.31mol (NaCl Na,aoo N 62. 7 62 . 7 K 62. 7 62 . 7 OH =2y=2yK K o ) Ag c c ,bb 21 2 2q C b 3 . 1 q 1 1 22 aa a b b 2 q 2 1 22 aa a b b 12 1 1 a q b 2 2 2 a q b 3 2 131212 22 2 22 aa
3、qqqqq C bbbb 2 8 0 0.11 ( 0.119)0.30V 1 0qc 10 1 212 ln2lnln r y RTRTRT RTc FCFF 1 1 y a qq C 10 22 ln2lnln r RTRTRT RTc FqFF 12 3 0.32 8.85 1040 298 8.31 0.05912log2log0.3log(10 ) 0.1 c 3 0.2220.0591log(10 )c 0.001cmol L 1 0.222V 1 2 :0.222:0.3 3 0.1cmol L 1 0.1038V 1 1 : 3 1 0 8 2 r F qcRTSh RT 1
4、2 F Z RT 3 2.648 10qcShZ 0.001cmol L 3 37.764 2.648 101 q ShZ 12 37.764ln 37.76437.76412.3log75.54.325ZSh 1 2 0.222 ZRT V F 0.1cmol L 1 0.1038V 9Cd0.37VNaCl0.25 0.27V ClNaClCl 10 lnlnTcTclnlnlnln FqFFFqFF 0.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.3
5、2 8.85 1040 298 8.310.32 8.85 1040 298 8.31 1a a qqqq 1 1 qq 0.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.32 8.85 1040 298 8.310.32 8.85 1040 298 8.31 0.2220.222V V 1: 0.222:0.3 1: 0.222:0.3:0.222:0.3 0.10
6、380.1038V ©right& 11 1 2 2CueCu25oTC 2 07 2.32.3 log0.337100.13 22 Cu RTRT aV FF 2 1 2 HeH25oTC0.130 ac 2.3 log0.0591log 2 0.1300.230.28 c H RT aV F 0.28V 2 2 22HeHlog6.5 H a , 0.0591log1.230.846 c HH aV 3 2 2ZneZn 2 2ZnZne 2 0 , 2.30.0591 log0.763log 0.1 0.150.817 22 Zna Zn RT aV F 22 2 HeH c
7、, 0.0591log0.0591log 0.2 0.2651.061.1354 cHH H aV c 1.135 c V , 0.8171.1350.318 ZncZn V V0.8171.1350.50.818 ac IRV 4BAB 0.00.20.40.60.81.0 0.0 0.1 0.2 0.3 0.4 0.5 5 1 j 2 j 1 11 exp w jnFvnfKc RT 2 22 exp w jnFvnFKc RT 3 2121 1 4 10 expexpexp0.193 8.31 293 jwww jRTRT 2 21 0.19318.6jj81% mA cm ZnZnZn
8、 0.8171.1350.50.8180.8171.1350.50.8180.8171.1350.50.818 0.0591log0.0591log 0.2 0.2651.061.13540.0591log0.0591log 0.2 0.2651.061.13540.0591log0.0591log 0.2 0.2651.061.13540.0591log0.0591log 0.2 0.2651.061.13540.0591log0.0591log 0.2 0.2651.061.13540.0591log0.0591log 0.2 0.2651.061.13540.0591log0.0591l
9、og 0.2 0.2651.061.1354 , ,ZnZnZnZn 0.8171.1350.50.8180.8171.1350.50.8180.8171.1350.50.8180.8171.1350.50.8180.8171.1350.50.8180.8171.1350.50.8180.8171.1350.50.818 B B ©right& 12 6 32 2 96500 1 10193jnFvA m 2 2 96500 0.2548250jnFvA m 2 193jA m 2 193jjA m 2 48250 19348057jjA m jjj 7 1 v 1 W 2 v 2
10、W 1 1 exp W vKc RT 2 2 exp W vKc RT 12 21 exp1000 WW vv RT 3 1221 lnln108.31 29817106WWWRTvvJ mol 17106J mol 8 2 0 2.30.0591 log0.763log 0.33 10.77 22 cZn Zn RT mV F 0 0 aH 0.777 ac EVV=1.24VVE Zn V ac EIRV1.240.7770.1640.10.199 ca EIRV 1 Cu 2 1d j 2d j 3d j 0 d c jnFD 32 2 dd jj 1dd jj 321dd jj 3 0
11、53 2 2 4 96500 6 100.1 10 0.046 5 10 d c jnFDA cm 4 2 Cd 2 Cd t c j 0.5 c j 1.240.7770.1640.10.1991.240.7770.1640.10.199 0.763log 0.33 10.770.763log 0.33 10.770.763log 0.33 10.770.763log 0.33 10.770.763log 0.33 10.770.763log 0.33 10.770.763log 0.33 10.770.763log 0.33 10.770.763log 0.33 10.77 1.240.7
12、770.1640.10.1991.240.7770.1640.10.1991.240.7770.1640.10.1991.240.7770.1640.10.1991.240.7770.1640.10.199 CuCu ©right& 13 5 0 0 0 0 s d d s x cc jj c j cc dc dx 52 0 2 96500 0.5 108 100.077 x 2 jnFD dc dxA cm 2.3 log 1 2 d RTj Fj 22 0.056 log 11.94 2.30.0577 d Fj jRT 10.0115 d j j 0 12 0.01150.02
13、3 s d j ccmol j L 6 023 2 2 2 96500 1 100.5 10 0.088 1.1 10 d c jnFDA cm 2.30.05910.044 log 1log 10.0099 20.088 c d RTj Vm nFj V 7 2 31 61 20 0.62 d jnFDc262.8ns 2 31 6 1 2 523 0.62 2 965001 101.09 1062.80.1 100.0935 d jA 2 cm 053 2 3 2 96500 1 100.1 10 0.0386 5 10 d c jnFDA cm 0.0935 2.42 0.0386 d
14、d j j 8 22 2202253 2 222 4965003.14 1.2 100.1 10 5.6 10 4 4 10.5 n FD c ts j 1 1 3 2 2 03 2 1 10 10.1 1018.66 10 5.6 10 s OO t ccmol 2 L 02 2 8.67 10 s OO jt ccmol L nFD 9 043 2 2 96500 1.5 100.1 10 0.2895 0.01 d c jnFDA cm 1 2 ln d RTjj nFj 1 2 2.30.05910.28950.08 log0.12log0.132 220.08 d RTjj V Fj
15、 2 0.2jA cm 1 2 2.30.05910.28950.2 log0.132log0.142 220.2 d RTjj V Fj nsnsns262.8262.8262.8262.8nsns262.8262.8 1 61 61 6 jA0.62 2 965001 101.09 1062.80.1 100.09350.62 2 965001 101.09 1062.80.1 100.09350.62 2 965001 101.09 1062.80.1 100.09350.62 2 965001 101.09 1062.80.1 100.09350.62 2 965001 101.09
16、1062.80.1 100.0935 0.00990.0099VmVm0.00990.00990.00990.0099 V 1 21 21 2 jAjA0.62 2 965001 101.09 1062.80.1 100.09350.62 2 965001 101.09 1062.80.1 100.09350.62 2 965001 101.09 1062.80.1 100.0935 1 21 21 2 0.62 2 965001 101.09 1062.80.1 100.09350.62 2 965001 101.09 1062.80.1 100.09350.62 2 965001 101.09 1062.80.1 100.0935 3 3 2 96500 1 100.1 102 96500 1 100.1 10 5 105 10 2 96500 1 100.1 102 96500 1 100.1 102 96500 1 100.1 102
