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1、Restricted Substance Testing Service 國際無鹵(Halogen Free)規範及趨勢介紹2007/11/28ShinJyh, Chen 陳新智陳新智RSTS E in some cases, this is morecost effective. halogen-free compliance are only required for components containing plastic materials. Testing is not required for parts that are made up entirely of metal al
2、loys or ceramics unless there is a known risk of these parts containing halogens.22Information form Dell23無鹵素要求-廠商規範 Dell (I)Dell Halogen-Free SpecificationA01-00 2007, July Revision History Changed title from “Guideline”to “Specification”, added references to existing “halogen-free”industry standar
3、ds, changed bromine and chlorine thresholds from 1000 ppm to 900 ppm (per IEC/IPC standards) “IEC/IPC standards” means oxygen flask combustion method24無鹵素要求-廠商規範 Dell (II)Dell Halogen-Free Specification900 ppmBr900 ppmClLimit in productItem Currently prohibits the use of PBBs and PDBEs (including De
4、caBDE) for all applications Prohibits the use of all other BFRs (including TBBP-A and HBCD) in plastic parts for desktops, notebook and server products as well as TCO certified displays and Blue Angel certified printers25Other information -Dell All parts and/or products designed to meet “halogen-fre
5、e” requirements. Homogenous material: a homogenous material is made up of one or more substances (e.g., an alloy is a homogenous material which in turn is made up of a number of substances). flame retardants not limited to, tetrabromobisphenol-A (TBBP-A), brominated epoxy oligomer (BEO) and polybrom
6、inated diphenyl ethers (PBDEs) notice：Fluorine(F), iodine(I), and Astatine(At) (other Group VIIA halogens) are not restricted in this definition26無鹵素要求-廠商規範 富士康ESD-A0RH-004 Rev. A900ppmBr1500ppmTotal halogens contained (Cl+Br)900ppmClLimitItem 建立在均值材料的基礎上 無鹵符合性測試報告, 只需要對含塑膠材料的部件/產品進 行測試, 除特殊case, 僅由
7、金屬合金或陶瓷製造的部件/產品 不需進行鹵素含量測試 不接受XRF測試報告27產品中鹵素的來源28含鹵素化合物用途-揮發性有機化合物 揮發性有機化合物(VOCs) 溶劑溶劑/助劑助劑 -二氯甲烷、氯苯、氯甲苯等 表面清洗劑表面清洗劑 冷煤冷煤 CFC、HCFC、Freon Halon-1211、Halon -1301：滅火器填裝，一九九四年國際公約規定海龍滅 火劑零生產、零消費 Freon-11：硬質PU發泡劑（例如冰箱絕緣層發泡體、建材）、PU合成皮（ 如汽車內裝材）、聚苯乙烯（PS）發泡劑（如建材）及PE發泡劑等，一般 大樓及廚房使用的大型空調離心式冰水機的冷媒 Freon-12：家用冷氣
8、機、漁船冷凍系統、商業冷凍系統及冷藏櫃 Freon-113：常用於跟高科技產品，如積體電路板、半導體材料等電子零件 及光學零件清洗劑 Freon 114 ：噴霧器的推進劑 (Propellant) ；冷煤 ( Refrigerant ) ；溶劑及除 脂劑 (Degreaser) ；吹泡劑 (Foam blowing agent) ；樹脂的單體29含鹵素化合物用途-半揮發性有機化合物 半揮發性有機化合物(SVOCs) 含溴化合物，作為阻燃劑阻燃劑用途，常見的阻燃劑： PBBs/PBDEs：PolyBromo Biphenyl/ PolyBromo Biphenyl ether TBBPA、TBB
9、PA-bis：TetraBromo Bisphenol A/ -bis HBCD：HexaBromoCycloDodecane BrPS：Brominated PolyStyrene 多用於印刷電路板、元件(如連接器)、塑膠件與電線 含氯化合物，多作為阻燃劑阻燃劑用途 PCB：PolyChloroBiphenyl，含氯阻燃劑，絕緣油 PCT：含氯阻燃劑 PCN：含氯阻燃劑 CP/SCCP(C10C13)：含氯阻燃劑，潤滑劑 用於染劑/顏料 PVC塑膠塑膠類，電線外皮 含氟化合物 PFOA/PFOS Telfon30為何要推動無鹵31含鹵素產品的危害 含溴/氯化合物電子廢料、塑膠產品主要添加物質
10、/種類：鹵素類阻燃劑、PVC 燃燒時亦會產生酸性氣體(HCl) 含溴/氯化合物電子廢料、塑膠產品燃燒時，易產有害物質戴奧辛戴奧辛，經由生物 累積，造成健康危害32燃燒過程與反應HeatFuelAirFireHeat transferMixing of fuel and airHeat transferFlame RetardantFlame Retardant33阻燃劑分類 無機類 Inorganic 含溴有機類含溴有機類Brominated organic 含氯有機類含氯有機類Chlorinated organic 有機磷酸類(磷酸酯)Organ phosphorus(mainly phos
11、phate esters) 鹵化有機磷類鹵化有機磷類Halogenated organ phosphorus(chlorinated and brominated, mainly phosphate esters) 有機氮類 Nitrogen-basedPRIORITISATION OF FLAME RETARDANTS FOR ENVIRONMENTAL RISK ASSESSMENT (Environment agency)P R Fisk, A E Girling and R J Wildey34常見耐燃劑種類Sb2O3三氧化二銻三氧化二銻DecaBDE 十溴聯苯醚(PBDEs grou
12、p)DecaBB 十溴聯苯(PBBs group)HBCD 六溴環十二烷TBBP-A 四溴雙酚ATPP 磷酸三苯酯Ethane-1,2-bis(pentabromophenyl)TribromoPhenol 三溴酚Reactive FRAdditive FR35全球阻燃劑品種消費結構比例%2884氯系阻燃劑8204030日本-76025亞洲7263524美洲10252833歐洲其他有機磷系阻燃劑溴系阻燃劑無機類阻燃劑地區36阻燃劑產品及應用Endcap for FR oligomerUV stable ABS2,4,6-TribromophenolBis(tribromophenoxy)eth
13、aneReactive FRPhenolHigh heat glass reiforced polyamideNon-blooming polypropylenePolydibromostyreneGrafted polybromostyrene on polypropyleneReactive FRStyrenePolyesterFlexible polyvinylchloride(PVC)Rigid PVCTetrabromophthalic anhydrideTetrabromophthalic esterTetrabromophthalate diolReactive FRPhthal
14、ic acid anhydridePolystyrene, polyester,HIPS, Glow wire, upholstered furnitureHexaBromoCycloDodecane(HBCD)Additive FRcyclododecaneFlexible and rigid polyurethaneABS,HIPSPBDEs : Penta mixPBDEs : Octa mix, DecaAdditive FRDiphenyl etherEpoxy and carylonitrile butadiene styrene (ABS) resignPolypropylene
15、, polyethylene, glow wire glass- fibre reinforced polybutylene terephthalate, polycarbonate sheetsTBBP-ABisphenol-A bisdibromopropyletherCarbonate oligomers of TBBP-AReactive FRBisphenol AApplicationExamplesTypeBFR product groupRef: J. De Boer,Envirom. Chem. 2004,1,81-8537含鹵化合物使用範圍-I磁帶(magnetic tape
16、)薄膜(film)、膠帶、聚酯薄膜線材的外被與包覆成型的外殼線材 PVC特定防火等級的樹脂薄膜(film)、膠帶、聚酯薄膜特定防火等級的PBT及PA樹脂連接器FR-4環氧樹脂、壓鑄複合物、塑 膠包材、防焊罩、熱緣介面材料、 沖模附著及充填電子零件FR-4環氧樹脂及防焊罩印刷電路板線材(cable/wire)的絕緣材料線材特定防火等級的ABS、PC、PS及 PBT樹脂塑膠機械件BFR應用範圍產品種類鹵素項目38阻燃劑產品及應用-ILabels, adhesives and tapesEMI gasketsPlastics partsInsulatorsFans or blowersDuck headsConnectorsIntegrated circuits or other electrical components with plastic packagesFlexible printed circuit boardsPrinted circuit bo
