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1、,热固性快速胶化聚氨酯的拉挤成型：加工过程和机械性能Pultrusion of Fast-GelThermoset Polyurethanes:Processing Considerations andMechanical Properties,Translation company :Beijing Jinghua Park polyurethane equipment Co., Ltd,热固性快速胶化聚氨酯的拉挤成型：加工过程和机械性能Pultrusion of Fast-Gel Thermoset Polyurethanes:Processing Considerations and M
2、echanical Properties,背景：复合材料企业Background: the Composites Industry实验策略Experimental Strategy-加工过程Processing-系统配置System Configuration-机械性能Mechanical Properties结果Results-加工过程 Processing-机械性能Mechanical Properties-区域和人员监测器Area & Personnel Monitoring结论Conclusions,什么是复合材料？What is a Composite?,广泛定义：两种材料的结合，仅
3、一种材料不能单独使用Broad definition: a combination of two materials that can do things neither could do alone工作定义：一种强韧的或坚硬的物质（经常是一种纤维）能够为基质（通常是树脂）提供重要的机械性能，从而保护纤维免受强度和环境的损坏。Working definition: a strong or stiff reinforcement (usually a fiber) that provides key mechanical properties to a matrix (usually a res
4、in) that in turn protects the fiber from stresses and environmental damage,工作定义覆盖了多样产品，如图所示The Working Definition Covers a HugeRange of Products,市场数据：Market Statistics:,美国年度复合材料总量（2000年）U.S. Annual Composites Output(Year 2000),240亿美金$24 Billion,39亿英镑（纤维和树脂）3.9 Billion Pounds(Resin & Fiber),全球年度总量预计是
5、美国的2.5倍（100亿英镑）Worldwide Annual Output is Estimated at2.5 Times US (10 Billion Pounds),树脂消耗占总体的65%（美国25亿英镑，全球65英镑）Resin Consumption Accounts for 65% of Volume(2.5 Billion Pounds US/ 6.5 Billion Pounds Worldwide),信息来源：复合物品制造业协会Source: Composites Fabricators Association,市场数据：Market Statistics：,历年复合材料市
6、场增幅（如图所示）Historic Composites Market Growth,信息来源：复合物品制造业协会Source: Composites Fabricators Association,市场数据：Market Statistics:,模具加工复合材料所占份额Composites Production byMarket Segment - 2001,信息来源：复合物品制造业协会Source: Composites Fabricators Association,市场大小分析Market Share by Size,50个大公司产量占35%,1200个中小公司产量占50%,4200个
7、小公司产量占15%,信息来源：复合物品制造业协会Source: Composites Fabricators Association,实验策略Experimental Procedure,聚醚多元醇、异氰酸酯、催化剂和脱模剂的分类Identification of candidate polyols, isocyanates, catalysts and mold releases加工特点的两相评估Two-phase evaluation of processing characteristics单相，可工作的化学物质分类Phase One: Identification of workabl
8、e chemistries两相 温度、加速包膜、化学计量学、脱模剂的开发Phase Two: Exploration of temperature & speed envelopes, stoichiometry & mold releases环境和工作的安全评估Parallel environmental & workplace safety evaluation机械性能特点Mechanical properties characterization,实验策略Experimental Procedure,聚醚多元醇、异氰酸酯、催化剂和脱模剂的分类Identification of candi
9、date polyols, isocyanates, catalysts and mold releases加工特点的两相评估Two-phase evaluation of processing characteristics单相，可工作的化学物质分类Phase One: Identification of workable chemistries两相 温度、加速包膜、化学计量学、脱模剂的开发Phase Two: Exploration of temperature & speed envelopes, stoichiometry & mold releases环境和工作的安全评估Parall
10、el environmental & workplace safety evaluation机械性能特点Mechanical properties characterization,JHPK-G20 Pultrusion Machine(JHPK-G20拉挤成型设备),Pultrusion Machine(拉挤成型设备JHPK-G20系列),一、设备的基本介绍：可应用于新型聚氨酯型材的拉挤生产，产品可完全替代玻璃钢拉挤型材，包括聚氨酯门窗型材、聚氨酯导槽、聚氨酯管及其它成型件。The general introduction and special function :applied in t
11、he new type polyurethane profile extruding production which can completely replace the fiberglass extruding profile, including the polyurethane profile of window and door, polyurethane guide groove, polyurethane pipe and other molding products.二、注胶(拉挤成型）设备必要的几点功能 1、设备对于温度控制的精准性 The accurancy of temp
12、erature controlling 2、AB组分比例控制的的准确性The accurancy of the ratio of the raw material 3、系统的稳定性：对与控制器及编程要求较高The stability of the system : accompanying system 4、拉挤线速度的探测性：能精准的反馈拉挤速度，根据拉挤线速度控制原料输出的多、少、停止The detectability of the speed : the accurancy of the speed feedback , high safety factor4、自动上料：保证原料处于充足
13、状态，确保连续生产。Automatically supply raw materil,拉挤工艺介绍the introduction of pultrusion technology,自动的连续的过程，通过拉着被树脂浸润的增强材料通过加热的模具来生产带一定横截面的复合材料的工艺。（牵引着被树脂浸润的增强材料通过加热的模具来生产带一定横截面的复合材料的工艺。its a automatic continuous process，through pulling the reinforcing materials that have been soaked with resin,then pass th
14、e heating moulds, in the end , produce some composites with transversal surface.its such kind of crafts .,拉挤钢模和加热装置Pultrusion Die and Heater Setup,90厘米钢模长度90 cm die length,钢模出口冷却（持续流动的水）Die entrance cooling (continuous flow tap water),在3个区域中有6个独立的加热器，带有闭合回路的控制器。Six independent resistance heaters in
15、3 zones with closed-loop controllers,25毫米空气隔阂25 mm air gap,拉挤系统配置（根据聚氨酯变化）Pultrusion System Configuration (Changes for Polyurethane),树脂灌注，纤维润湿室Resin injection/fiber wetting chamber高密度聚乙烯（HDPE）Machined from HDPE模具入口面板Bolted/sealed to die entrance face树脂计时和混合Resin metering and mixing商业计时和混合传动装置系统（车床喷涂
16、设备）（螺旋缠绕喷涂设备）Commercial meter/mix gear pump system (truck-bed-liner spray equipment)气动混合枪头带有一次性静态搅拌器（静态混合器）Air-actuated mix head with 30-element disposable static mixer,树脂灌注器和纤维润湿室Resin Injector/Fiber Wetting Chamber,树脂灌注器和纤维润湿室Entrance plate to reduce resin loss入口设置：减少入口树脂损失Exit matches shape and area of die entrance长度：30厘米Length: 30 cm入口出口区域比例：6：1Entrance/Exit area ratio = 6:1,
