表面活性剂在电池材料中的应用

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1、Jan. 2011 现代化工311Modern Chem ical Industry 2011M1V4宋金梅,张玉秀,朱书全,王一卉,朴春爱(中国矿业大学(北京 )化学与环境工程学院,北京 100083)K1:V4VM,_a3K,AVnullQnull,RvTb8V4!llZb1oM:V4;ms|: O69nullDSM: AnullcI|: 0253- 4320( 2011)01- 0028- 04Application of surfactant in battery materialSONG Jinnullmei, ZHANG Yunullxiu, ZHU Shunullquan, WA

2、NG Yinullhui, PIAO Chunnullai( School of Chemical and EnvironmentalEngineering, ChinaUniversity ofM ining&Technology ( Beijing), Beijing 100083, China)Abstract: Surfactant plays an important role in changing crystal form of metal oxide, inhibiting the hydrogenevolution, passive growth of dendrite an

3、d suppressing corrosion, and it can delay the electrode passivation, and emulsionprepared by surfactant and can act as a micronullreactor and prevent the agglomeration of nanoparticles and so on. Theadvance in application of surfactant in preparation of batterymaterial and recycling ofwaste batterie

4、s is indicated.K ey words: surfactant; batterymateria;l applicationnulll: 2010- 09- 02;R: 2010- 11- 09null:SEnull 863null( 2009AA06Z320);1S( 50874112)nullTe:( 1975- ),o,pV3,1VYs4;f(1962- ),o,pV,q,pV3=,1VYV4, 010- 62331792, zhangyuxiu cumtb. edu. cn, yxzhang9 sina. combnull nullo?h0,7?s CTAB SDSh12b1

5、!Pt/Cb4?,M/,TritonX-100?aSDBSaSDSa-1a4-&Y)bZEMMEaEa1FEaEa-Eb2null1nullTSDBSaCTABaTriton X-100Brij56C16H33(OCH2CH2) 8HV?MnO2bSDBSMnO2?ET, CTAB4?, Triton X- 100zb?13,7Brij56TA,E,)MnO2VCz?b14bP123, 4-&Y), CTABaAsYV!bP123,-ELiCoO2z?,e, 15b4-&Y), FeCl34,;-6(S-PPy),TLi/S-PPy,?abz416bCTAB,ELiFePO4THb4,hl17

6、bALiFePO4,)TiO2 /FFLiFenullPO4 /TiO2,.d?,700Q+,rqVr100%,0,z18bV,V4!vT,A4!LiFePO4 /TiO2?zb2null2nullTV4VeRvl,P8,Ved#,4?bUlagappan19K*0V42-Y-2)4d,d3null2 nmb|0V4CTABeVCuOV,9vCuOA(20bCTABVe-d#,4? 21bV4KxTbTritonX-100X?eCu-SnRvl,Cu-Sn,0F0,VI1 22bcYd0V4_F4?Ah1b,HVa? 23bcP123Y?A,=/,/,|T0B,M1,AUF? 24bnull

7、null (上接第 27页)29 Nagura M, Nomura Y, Gotok Y, et al. Antinullthrombogenicity ofstyrenenull butadienenullstyrene triblock copolymer grafted w ith poly(ethylene glycol) s J. J ApplPolym Sc,i 2009, 113( 4): 2462-2476.30 RamesanM T, Mathew G, KuriakoseB, etal. Role ofdichlorocarbenullnemodified styrene

8、butadiene rubber in compatibilisation of stynullrene butadiene rubber and chloroprene rubber blends J. EurPolym J, 2001, 37( 4): 719- 728.31 FuH Y, XieL D, Dou DY, et al. Storage stability and compatibilityof asphaltbindermodified by SBS graft copolymer J. Construcnulltion and BuildingM aterials, 20

9、07, 21( 7): 1528- 1533.32 ColtelliMnullB, M aggiore I D, SaviS, et al. M odified styrenenullbutadinullenenullstyrene block copolymer as compatibiliser precursor in polyethnullylene/poly( ethylene terephthalate) blends J. Polym DegradStab, 2005, 90( 2): 211- 223.33 Guo H G, He J D, Fu Z. Study on SBR grafted with maleic annullhydride(SBRnullMAH) as compatibilizer in the blend ofPVC/SBRJ. Hecheng Shuzhi Ji Suliao/China Synthetic Resin and Plasnulltics, 1998, 15( 1): 38- 40. nullnull29null现代化工3113nullK4a1bYTp1yBbCB1bb,7OFMbyN,A!Eh|b-a

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