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1、.专业整理.无机化合物的标准热力学数据Standard Thermodynamic Data of Inorganic Compounds下表中的标准热力学数据是以温度25.0（298.15K）处于标准状态的1摩尔纯物质为基准的。物质状态表示符号为：g气态，l液态，cr晶体。Hf 物质的标准生成焓（298.15K）,单位为kJ/mol； Gf 物质的标准生成Gibbs自由能（298.15K）,单位为kJ/mol； S 物质的标准熵（298.15K）,单位为J/（molK）； Cp 物质的常压热容（298.15K）,单位为J/(molK)。 序号(No.) 分子式(Molecular formu
2、la) 状态(State) Hf /(kJ/mol) Gf /(kJ/mol) S /J/(molK) Cp /J/(molK) 1 Ac cr 0.0 - 56.5 27.2 g 406.0 366.0 188.1 20.8 2 Ag cr 0.0 - 42.6 25.4 2 Ag g 284.9 246.0 173.0 20.8 3 AgBr cr -100.4 -96.9 107.1 52.4 4 AgBrO3 cr -10.5 71.3 151.9 - 5 AgCl cr -127.0 -109.8 96.3 50.8 6 AgClO3 cr -30.3 64.5 142.0 - 7
3、AgClO4 cr -31.1 - - - 8 AgCN cr 146.0 156.9 107.2 66.7 9 Ag2CO3 cr -505.8 -436.8 167.4 112.3 10 Ag2CrO4 cr -731.7 -641.8 217.6 142.3 11 AgF cr -204.6 - - - 12 AgI cr -61.8 -66.2 115.5 56.8 13 AgIO3 cr -171.1 -93.7 149.4 102.9 14 AgNO3 cr -124.4 -33.4 140.9 93.1 15 Ag2O cr -31.1 -11.2 121.3 65.9 16 A
4、g2S cr -32.6 -40.7 144.0 76.5 17 Ag2SO4 cr -715.9 -618.4 200.4 131.4 18 Al cr 0.0 - 28.3 24.4 g 330.0 289.4 164.6 21.4 19 AlBr3 cr -527.2 - - 101.7 g -425.1 - - - 20 AlCl3 cr -704.2 -628.8 110.7 91.8 g -583.2 - - - 21 AlF3 cr -1510.4 -1431.1 66.5 75.1 g -1204.6 -1188.2 277.1 62.6 22 AlI3 cr -313.8 -
5、300.8 159.0 98.7 g -207.5 - - - 23 Al2O3 cr -1675.7 -1582.3 50.9 79.0 24 AlPO4 cr -1733.8 -1617.9 90.8 93.2 25 Al2S3 cr -724.0 - - - 26 Am cr 0.0 - - - 27 Ar g 0.0 - 154.8 20.8 28 As (灰,gray) cr 0.0 - 35.1 24.6 As(黄,yellow) cr 14.6 - - - As(黄,yellow) g 302.5 261.0 174.2 20.8 29 AsBr3 cr -197.5 - - -
6、 g -130.0 -159.0 363.9 79.2 30 AsCl3 l -305.0 -259.4 216.3 - g -261.5 -248.9 327.2 75.7 31 AsF3 l -821.3 -774.2 181.2 126.6 g -785.8 -770.8 289.1 65.6 32 AsH3 g 66.4 68.9 222.8 38.1 33 AsI3 cr -58.2 -59.4 213.1 105.8 g - - 388.3 80.6 34 As2O5 cr -924.9 -782.3 105.4 116.5 35 As2S3 cr -169.0 -168.6 16
7、3.6 116.3 36 At cr 0.0 - - - 37 Au cr 0.0 - 47.4 25.4 g 366.1 326.3 180.5 20.8 38 AuBr3 cr -53.3 - - - 39 AuCl3 cr -117.6 - - - 40 AuF3 cr -363.6 - - - 41 AuI cr 0.0 - - - 42 B cr 0.0 - 5.9 11.1 g 565.0 521.0 153.4 20.8 43 BBr3 l -239.7 -238.5 229.7 - g -205.6 -232.5 324.2 67.8 44 BCl3 l -427.2 -387
8、.4 206.3 106.7 45 BF3 g -1136.0 -1119.4 254.4 50 46 BH3 g 100.0 - - - 47 B2H6 g 35.6 86.7 232.1 56.9 48 BI3 g 71.1 20.7 349.2 70.8 49 B2O3 cr -1273.5 -1194.3 54.0 - g -843.8 -832.0 279.8 66.9 50 B2S3 cr -240.6 - - - g 67.0 - - - 51 Ba cr 0.0 - 62.8 28.1 g 180.0 146.0 170.2 20.8 52 BaBr2 cr -757.3 -7
9、36.8 146.0 - 53 BaCl2 cr -858.6 -810.4 123.7 75.1 54 BaCO3 cr -1216.3 -1137.6 112.1 85.3 55 BaF2 cr -1207.1 -1156.8 96.4 71.2 56 BaH2 cr -178.7 - - - 57 BaI2 cr -602.1 - - - 58 Ba(NO2)2 cr -768.2 - - - 59 Ba(NO3)2 cr -992.1 -796.6 213.8 151.4 60 BaO cr -553.5 -525.1 70.4 47.8 61 Ba(OH)2 cr -944.7 -
10、- - 62 BaS cr -460.0 -456.0 78.2 49.4 63 BaSO4 cr -1473.2 -1362.2 132.2 101.8 64 Be cr 0.0 - 9.5 16.4 g 324.0 286.6 136.3 20.8 65 BeBr2 cr -353.5 - - - 66 BeCl2 cr -490.4 -445.6 82.7 64.8 67 BeCO3 cr -1025.0 - - - 68 BeF2 cr -1026.8 -979.4 53.4 51.8 69 BeI2 cr -192.5 - - - 70 BeO cr -609.4 -580.1 13
11、.8 - 71 Be(OH)2 cr -902.5 -815.0 51.9 - 72 BeS cr -234.3 - - - 73 BeSO4 cr -1205.2 -1093.8 77.9 85.7 74 Bi cr 0.0 - 56.7 25.5 g 207.1 168.2 187.0 20.8 75 BiCl3 cr -379.1 -315.0 177.0 105.0 g -265.7 -256.0 358.9 79.7 76 BiI3 cr - -175.3 - - 77 Bi(OH)3 cr -711.3 - - - 78 Bi2O3 cr -573.9 -493.7 151.5 113.5 79 Bi2S3 cr -143.1 -140.6 200.4 122.2 80 Bk cr 0.0 - - - 81 Br g 111.9 82.4 175.0 20.8 82 BrF3 l -300.8 -240.5 178.2 124.6 g -255.6 -229.4 292.5 66.6 83 BrF5 l -458.6 -351.8 225.1 - g -428.9 -350.6 320.2 99.6 8
