《表面引发聚合反应研究进展》由会员分享，可在线阅读，更多相关《表面引发聚合反应研究进展（7页珍藏版）》请在金锄头文库上搜索。
1、表面引发聚合反应研究进展*倪null 刚null 杨null 武* * null 何晓燕null 薄丽丽null 吕维莲(西北师范大学化学化工学院甘肃省高分子材料重点实验室兰州null 730070)Knull1null 表面引发聚合反应作为一种新的聚合反应可广泛应用于固体基底的表面修饰与改性b结合分子自组装技术,几乎各种类型的聚合反应都有可能在固体基底表面进行b本文对表面引发聚合反应的研究进展进行了综述,对反应类型a实验方法a研究动向以及在合成聚合物刷a形成图案化聚合物薄膜等方面的应用与发展前景作了介绍与讨论b1oMnull 表面引发聚合反应null 自组装单分子层null 图案化聚合物薄膜
2、null 聚合物刷ms|: O631. 5 nullDSM: A nullcI|: 1005-281X(2005)06-1074-07Advances in Surface Initiated PolymerizationNi Gang null Yang Wu* * null HeXiaoyan null Bo Lili null LnullWeilian(College of Chemistry and Chemical Engineering, Northwest Normal University,Gansu Key Laboratory of Polymer Materials, L
3、anzhou 730070, China)Abstractnull The recent developments of surface initiated polymerization are reviewed. Surface modification of thepolymers is an important area both for application and basic research. As a new kind of controlled polymerizationtechniques, surface initiated polymerization can be
4、used to modify the surfaces of the solid materials and tailor substrateproperties. It opens a new way for the modification of solid substrates for their potential applications in a variety oftechnological fields. The theoretical and the experimental approaches and the research prospects of the surfa
5、ce initiatedpolymerization are extensively introduced in this paper. The applications of this technique including the patternednanostructures of polymer films and polymer brushes are also discussed in detail.Key words null surface initiated polymerization; sel-f assembled monolayer; patterning polym
6、er films; polymerbrushesnull nulll: 2004M11,l: 2005M1null *SE1S(No.20475044),M=9#=SvMS/7(KJCX-01)* *Ynull e-mail: yangw nwnu. BanulleVBYrVZEbVBZT: null( grafting to)nullEnullV(grafting from)nullE 1 ,-Q2?vYV 2o3null 5V;5V?Q( surface initiatedpolymerization, SIP)L 6bV?Q5VQ?,V?8QbZEM1,Hls08L9,rXnullnul
7、lELVH8p 7bV83Q,AE,8l8rV9,d,y7%Za4|_aas(aVbLCV?H,VYVMQHWHq,zebN1762005M11化null 学null 进null 展PROGRESS IN CHEMISTRYVol. 17 No. 6null Nov. , 2005YVi?,V=Q?Q3,LCV9,V7!V,ZLLCV?ebSIP?ZEVE8 ,9Vs01F/1Fs0(SAMs)E 9,10bVV%o1Fs0,|_a%aQ?,y7dr-ZEb1SAMsESIP8b=aV?Q?3V?QV 11, 12a 13%8VbVeVZSbCSIP,KSi 14null 16aAu 17,1
8、8aA 19, 20aj 21aAl 22aPt 23aAl2O3 24aTr 25, 26adA27, 28adjr 29a8 30a, 31aTiO2%x 32aJAUTiO2 33aCdS 34aMnFe2O4 35b1F/K,-aK,vS|SIP?ZBZ_baV?QSAMsESIPVVYVo1Fs0,?41Fs0%?3Q,V|?s1Fs01Fs02?ve,null?4-1Fs0nullb+QV?M%8Vb 7;V?QT,/V?QZTtb1.V?B1QV?B1Q 36null 38VF;vHq/31?QbBaker 24AuVYVdJA(MPS)1FJA3Q?4s0bFHq/,sss31,?&YQobSchmid 39AuVYV1F4, 4null-=(1, 10-=H)-4-e,o300nm,;v/,?&YQVmb2.V?1Qvm40s,V?1QV%s/+: (1)?-4( iniferter)V?1QbHadziioannou41ZEjA!r100nm&Y(PS)&Y-JdJ( PS- b-PMMA)b( 2)1(TEMO)V?1Q 42, 43bMulfort422, 2, 6, 6-J-1-J1(TEMPO)1Fo2?vQ,?41v,YVV?
