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1、2H+ H+ OXALOACETATE PYRUVATE SUCCINYL-CoA GLUTARATE CITRATE MALATE 2-OXO- ASPARTATE NO2- NO3- N2 NH4 CH3COSCoA ACETYL-CoA HOH CO2 NAD T R A N S A M I N A T I O N 2H+ 2H + + CO2 5-Amino- levulinate Glycine H+ H+ H+ H+ H+ H+ c H+ H+ a F0 F1 F1 2 1 1 0 c - s u b - u n i t s A D P + P i H+ 3 . 6 . 1 . 3
2、 4 H + - t r a n s p o r t i n g A T P s y n t h a s e F6 oscp ATP ADP + Pi FUMARATE UQH2 UQ UQH2 NADH+H+ CH2COO- C(OH)COO- CH2COO- CH(OH)COO- CHCOO- CH2COO- -OOCCOCH2CH2COO- -OOCCH2CH2CO.SCoA -OOCCOCH2COO- CH3CH(OH)CH2CO.SCoA -OOCCH=CHCOO- Glyoxylate Cycle -OOCCHO GTP GDP ATP + HEMEProtoporphyrinog
3、enCoproporphyrinogenUroporphyrinogenPorphobilinogen 5-Amino- levulinate COO- CH2 CH2 H2NCH2C=O FADH2 FAD Cyt.b Fe-S SUCCINATE II CH3COCOO- PYRUVATE Pi XY Cyt.c1 Fe-S 2e- 2e- 1e- 1e- III 2UQUQ UQH2 2UQH2 2UQ._ UQ._ Cyt.bLCyt.bH Cyt.c IV CuA CuB CuA 1.9.3.1 2e- Heme a Heme a3 2H+ 2H+ 4H+ 4H+ 2H+ NAD+
4、NADH+H+ NAD+ 1.1.1.39 1.2.4.1 2.3.1.12 3.1.3.43 4.1.1.32 4.1.3.7 4.2.1.3 1.1.1.41 1.2.4.2 2.3.1.61 6.2.1.4 -OOCCH2CH2COO- 1.3.5.1 4.2.1.2 1.1.1.37 6.4.1.1 4.1.3.8 4.1.3.1 4.1.3.2 ISOCITRATE 2.6.1.1 2.3.1.16 4.1.1.71 1.2.1.16 5.1.99.1 5.4.99.2 4.3.1.1 1.4.1.2 1.4.1.14 6.3.5.4 1.6.6.1 1.7.99.4 1.7.7.1
5、 1.6.6.4 1.18.6.1 2.3.1.37 1.10.2.2 1.10.2.2 33 A T P ADP E N D E RG ON IC R EA C TI O N 1.6.5.3 I FMNH2 FMN I 1.6. 5.3 2Fe -S (5 Clusters) H+H+ H+H+ ATP 4H+ 2H+ 2H+ or H+ PHOTO- SYSTEM l O2 3.6.1.34 NADP+ Glyceraldehyde Ribulose-1,5-bis-P 2 8 8 H+ c 3 2 a 3 2 1 2 1 3 3 H+ H+ H+ H+ H+ H+ H+ H+ H+ H+
6、 H+H+ H+ H+ H+ H+ H+ H+ H+ H+ H+ H+ H+ H+ H+ H+ H+ H+H+ H+H+ H+H+H+ Translocated protons H+ H+ H+ H+ Pi Ferredoxin 4H+ PCPC PC PQH2 2PQH2 PQ_. 2PQ_. Fe-S Cyt.f PQ 2PQ Cyt bf 2e- 1e- 1e- 2e- 2e- 2e- 2e- C y cl ic P h o t o p h o s p h o r yl a ti o n PQ PHOTO- SYSTEM II Cyt bc N o n - c y c li c e l
7、e c t r o n f l o w 2e- 2e- Mn 2e- * Protons from Water H2O H+ H+ 2H+ 2H+ ATP synthase CO2 Fixation H+ ADP Pi H+ NADPH+H+ ATP THYLAKOID MEMBRANE CHLOROPLAST OUTER MEMBRANE THYLAKOID LUMEN STROMA ( e l e c t ri c c u r r e n t ) P680 Chl.a QA QB Pheophytin P700 Chl.A0 A1 Fe-S ATP ADP ATP 1/2O2 H2O PQ
8、H2 To Brain - A M I N O A C I D S P Y R I M I D I N E S P U R I N E S C A T E C H O L A M I N E S A R O M A T I C A M I N O A C I D S hv VISION L I P I D P H O T O S Y N T H E S I S P O R P H Y R I N S S T E R O I D S I S O P R E N O I D S P H O S P H O L I P I D S D E G R A D A T I O N L I P I D B
9、I O S Y N T H E S I S P E N T O S E S H E X O S E S P O L Y S A C C H A R I D E S CO CH CH(NH )COO 23 + FOLIC ACID C1 POOL VALINE ATP ATP 4.1.1.41.1.1.30 CH COCH 33 CH COCH COO 32 CH CH(OH)CH COO 32 3-OH-ButyrateAcetone Acetoacetate KETONE BODIES HYALURONIC ACIDDERMATAN BLOOD GROUP SUBSTANCES PEPTID
10、O- GLYCAN N-Ac-Neuraminate (Sialate) UDP- Iduronate UDP-N-Ac- Galactosamine UDP- Galacturonate GDP-Fucose TDP-Rhamnose ADP- Glucose UDP-Glucose TDP-4-Oxo- 6-deoxyglucose MANNOSE CHITINCHONDROITINPECTIN ALGINATES INULINCELLULOSE O-ANTIGENSSTARCHGLYCOGEN LACTOSE GALACTOSE O OH HO OH OH CH3O OPPT O OH
11、OH O OH ACNH HO OH O OHHO OPPU NHAC OH OHOH OH HO OH NHCOCH OH HO O OPPG CH OH 2 HO P UDP-N-Ac- Glucosamine pyruvate N-Ac-Mannosamine-6-P UDP-Glucuronate GDP-Mannose N-Ac-MannosamineUDP-N-Ac-Glucosamine N-Ac-Glucosamine-6-P Sorbitol Fructose-1-P Erythrose-4-P 3-Dehydrogulonate L-Xylose L-Lyxose D-Xy
12、lulose D-Ribose Ribitol L-ArabitolL-Xylulose L-RibuloseL-Ribulose-5-P L-Xylulose-5-P L-ArabinoseXylitolD-Xylose D-ArabinoseD-Ribulose ASCORBATE 2, 3-Dioxogulonate N-Ac-Glucosamine-1-P Inositol-PInositolGlucuronateGulonate Gulonolactone2-Oxogulonolactone Fructose 6-P-Gluconate D-Ribulose-5-P D-Xylulo
13、se-5-P Mannose-1-P GDP-Glucose TDP-Glucose UDP-Galactose Galactose-P Glucose-1-P Glucose-6-P Fructose-6-P Fructose- 1:6-bis-P OH HHH O HOCH2CCCCCO OH OHHOH HH O HOCH2CCCCOCO OHH H OH H CC OH CO P-Ribosyl amine Glycerate 2, 3-Diphospho- glycerate 3-P-Glyceraldehyde 1:3-bis-P-Glycerate 3-P-Glycerate 2
14、-P-Glycerate P-enolpyruvate Inositol CH OH 2 CH OH 2 HOCH CH OH 2 CH O 2 HOCH P Glycerol UDP-Galactose UDP-Sugars CH CH OH 32 ETHANOL Dihydroxy- acetone-P (Glycerone-P) Glucosamine-6-P Phospho- serine Chain elongationMitochondrial Serine Serine Indole-3-glycerol-P 3-Deoxy-D-arabino- heptulosonate-7-
15、P Indoleacetate (Auxin) Indoxyl FormylkynurenineKynurenine3-Hydroxy kynurenine 3-Hydroxy anthranilate 2-Amino-3-carboxy muconate semialdehyde NH OH Tryptamine1-(o-Carboxy phenylamino) 1-deoxyribulose-5-P N-(5-P-Ribosyl) anthranilate Anthranilate Catechol NH Indole- acetaldehyde NH CH CHO 2 Indolepyr
16、uvate NH C-CH(OH)CH(OH)CH O 2P CH 2-Aminomuconate- 6-semialdehyde CH CH NH 222 NH 1.2.3.7 4.1.1.43 3.5.1.93.7.1.3 4.2.1.20 1.13.11.64.1.1.45 2.4.2.18 4.6.1.4 4.1.1.48 1.14.13.9 4.6.1.3 Dehydro- quinate 4.2.1.10 1.1.1.252.5.1.19 Shikimate-3-PShikimate-5 enolpyruvate 3-P Chorismate PEP 2.7.1.71 1.4.1.19 HomogentisatePhenylpyruvate Cinnamate Coumarate Prephenate 2-Amino muconate FumarateAspartate GLYCINE Sarcosine Hydroxy- pyruvate P-Hydroxy- pyr
