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1、 Europe Acrylate Monomer Industry 2016 Market Research ReportChapters1 Industry Overview1.1 Definition and Specifications of Acrylate MonomerAcrylate monomers are esters which contain vinyl groups, that is, two carbon atoms double-bonded to each other, directly attached to the carbonyl carbon.Acryla
2、te monomers are key components in the formulation of coatings, inks, and adhesives. They react fast, which is very important in rapid cure technologies like UV/EB curing.Figure Chemical Structure Picture of Acrylate MonomerSource: QYR Chemical & Material Research Center, Sep 2016Table Product Specif
3、ications of Acrylate Monomer (Butyl Acrylate)Butyl AcrylateCAS Number.141-32-2Molecular Weight:128.2DescriptionButyl acrylate is clear, colorless liquid with a fruity odor. It is freely miscible with most organic solvents.Product SpecificationsValueTest MethodAssay, % min99.5ED-057Water, % maximum0.
4、05ED-070Acid Content (calculated as acrylic acid), % maximum0.01ED-096Color ex works, maximum10ED-071Inhibitor content (MeHQ1), ppm15 5ED-072Physical PropertiesBoiling Point, Cca. 148Freezing Point, Cca. 64Density 20C, g/cm30.898Refractive Index nD 20C1.415Heat of polymerization, kJ/kg504Vapor Press
5、ure: 0C, mbar1.0 20C, mbar4.3 50C, mbar25.5 100C, mbar228 200C, mbar3620Flash Point (Tag closed cup), C40.0Autoignition Temperature, C267Explosion Limits (vapor in air), % volume1.59.9Latent Heat of Evaporation boiling point, kJ/kg278.9Viscosity: 20C, mPas0.75 40C, mPas0.50 60C, mPas0.45 80C, mPas0.
6、37Solubility of butyl acrylate in water 25C, g/100g0.2Solubility of water in butyl acrylate 25C, g/100g0.7SafetyGeneralThe usual safety precautions when handling chemicals must be observed. These include the measures described in Federal. State and Local health and safety regulations thorough ventil
7、ation of the workplace good skin care and wearing of protective goggles.Material Safety Data SheetA Material Safety Data Sheet has been compiled for butyl acrylate that contains up-to-date information on all concerns relevant to safety.Industrial HygieneRefer to the Material Safety Data Sheet for bu
8、tyl acrylate for information regarding industrial hygiene.LabellingRefer to the Material Safety Data Sheet for butyl acrylate for information regarding labellingStorage and HandlingIn order to present polymerization, butyl acrylate must always be stored under air and never under inert gases. The pre
9、sence of oxygen is required for the stabilizer to Function effectively. It has to contain a stabilizer and the storage temperature must not exceed 35. Under these conditions, a storage stability of one year can be expected. In order to minimize the likelihood of over storage, the storage procedure s
10、hould strictly fallow the first-in-first-out principle. For extended storage periods over four weeks, it is advisable to replenish the dissolved oxygen content.Storage tanks and pipes should be made of stainless steel or aluminium.Although butyl acrylate does not corrode carbon steel, there is a ris
11、k of contamination if corrosion does occur.Regulations for the storage of flammable liquids must be observed (explosion-proof electrical equipment, vented tanks with flame arresters etc.) Storage tanks, pumps and pipes must be earthed.Source: QYR Chemical & Material Research Center, Sep 20161.2 Clas
12、sification of Acrylate MonomerTable Classification of Acrylate MonomerN.O.TypeCAS number1Methyl Acrylate96-33-32Ethyl Acrylate 140-88-53Butyl Acrylate141-32-242-Ethylhexyl Acrylate29590-42-95OtherSource: QYR Chemical & Material Research Center, Sep 2016Figure Europe Sales Market Share of Acrylate Mo
13、nomer by Product Types in 2015Source: QYR Chemical & Material Research Center, Sep 20161.2.1 Methyl AcrylateMethyl acrylate monomer offers significant advantages as an additive in copolymer-based adhesives, fibers, non-acrylic polymers (food packging), and plastics. It is also used as the starting b
14、lock for anti-oxidants and amino esters.1.2.2 Ethyl AcrylateEthyl Acrylate Monomer offers significant advantages as an additive in a wide range of copolymer-based finishes, coatings, adhesives, inks, lubricants, sealants, saturants, and plastics.1.2.3 Butyl AcrylateButyl Acrylate Monomer offers sign
15、ificant advantages as an additive in a wide range of copolymer-based finishes, coatings, adhesives, inks, lubricants, saturants, and plastics.1.2.4 2-Ethylhexyl Acrylate2-Ethylhexyl acrylate monomer offers significant advantages as an additive in copolymer-based pressure-sensitive adhesives, coatings and finishes.1.3 Applications of Acrylate MonomerTable Applications of Acrylate MonomerNo.ApplicationDetailExample1AdhesivesAcryla
